Dielectric and impedance characteristics of Na1/3Ca1/3Y1/3Cu3Ti4O12 ceramic prepared by solid-state reaction method

被引：16

作者：

Liu, Yang ^{[1
]}

Zhao, Xuguang ^{[1
]}

Zhang, Chujun ^{[1
]}

机构：

[1] Shaoguan Univ, Sch Civil Engn, Shaoguan 512005, Peoples R China

来源：

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS | 2016年 / 27卷 / 11期

关键词：

CACU3TI4O12; BARRIER; ACU(3)TI(4)O(12); CONSTANT; PERMITTIVITY; TEMPERATURE;

D O I：

10.1007/s10854-016-5314-7

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

Dielectric response of Na1/3Ca1/3Y1/3Cu3Ti4O12 ceramic, fabricated via a conventional solid-state method, has been investigated in the frequency range 100-2 MHz at temperatures from -80 to 200 A degrees C. Single phase of Na1/3Ca1/3Y1/3Cu3Ti4O12 with cubic perovskite-related structure was confirmed by X-ray diffraction. High dielectric permittivity (> 3 x 10(3)) and low dielectric loss (similar to 0.08) were observed at room temperature. The dielectric relaxation peaks of shifts to higher frequencies, indicating a thermally activated relaxation process. The activation energy for the dc conduction process (0.501 eV) is comparable to that for conduction at the grain boundaries (0.514 eV), indicating the dc conduction process is closely associated with the characteristics of grain boundaries in Na1/3Ca1/3Y1/3Cu3Ti4O12 ceramic.

引用

页码：11757 / 11761

页数：5

共 25 条

[1]

Adams TB, 2002, ADV MATER, V14, P1321, DOI 10.1002/1521-4095(20020916)14:18<1321::AID-ADMA1321>3.0.CO

[2]

2-P

[3]

Fang TT, 2007, J AM CERAM SOC, V90, P638, DOI [10.1111/j.1551-2916.2006.01419.x, 10.1111/j.1551-2918.2006.01419.x]

[4] Giant Dielectric-Permittivity Phenomena of Compositionally and Structurally CaCu3Ti4O12-Like Oxide Ceramics [J].

Hao, Wentao ;

Zhang, Jialiang ;

Tan, Yongqiang ;

Su, Wenbin .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2009, 92 (12) :2937-2943

[5] Microwave assisted sintering of CaCu3Ti4O12 [J].

Hutagalung, Sabar D. ;

Ikhwan, M. ;

Ibrahim, M. ;

Ahmad, Zainal A. .

CERAMICS INTERNATIONAL, 2008, 34 (04) :939-942

[6] A Novel Route to Greatly Enhanced Dielectric Permittivity with Reduce Loss Tangent in CaCu3-xZnxTi4O12/CaTiO3 Composites [J].

Jumpatam, Jutapol ;

Putasaeng, Bundit ;

Yamwong, Teerapon ;

Thongbai, Prasit ;

Maensiri, Santi .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2014, 97 (08) :2368-2371

[7] Study of structural, dielectric and electrical conduction behaviour of Gd substituted CaCu3Ti4O12 ceramics [J].

Kashyap, Raman ;

Thakur, O. P. ;

Tandon, R. P. .

CERAMICS INTERNATIONAL, 2012, 38 (04) :3029-3037

[8] Na1/3Ca1/3Bi1/3Cu3Ti4O12: A new giant dielectric perovskite ceramic in ACu3Ti4O12 compounds [J].

Kum-onsa, Pornsawan ;

Thongbai, Prasit ;

Putasaeng, Bundit ;

Yamwong, Teerapon ;

Maensiri, Santi .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2015, 35 (05) :1441-1447

[9] Origin(s) of the apparent high permittivity in CaCu3Ti4O12 ceramics: clarification on the contributions from internal barrier layer capacitor and sample-electrode contact effects [J].

Li, Ming ;

Shen, Zhijian ;

Nygren, Mats ;

Feteira, Antonio ;

Sinclair, Derek C. ;

West, Anthony R. .

JOURNAL OF APPLIED PHYSICS, 2009, 106 (10)

[10] Giant Dielectric Constant and Good Temperature Stability in Y2/3Cu3Ti4O12 Ceramics [J].

Liang, Pengfei ;

Yang, Zupei ;

Chao, Xiaolian ;

Liu, Zonghuai .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2012, 95 (07) :2218-2225

← 1 2 3 →