An Operationally Simple and Scalable Approach to Functionalized Ionic Liquids from Phosphonium and N-Heterocyclic Halide Salts

被引:2
作者
Meyer, Christopher J. [1 ]
Vogt, Monika [1 ]
Catalino, James P. [1 ]
Ashfeld, Brandon L. [1 ]
机构
[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46637 USA
关键词
ionic liquids; heterocyclic anions; phosphonium salts; imidazolium salts; triazolium salts; NATURAL AMINO-ACIDS; GREEN SOLVENTS; AZOLATE ANIONS; LOW-VISCOSITY; CO2; CAPTURE; BIOCATALYSIS; EXTRACTION; SEPARATION; CATALYSIS; MEMBRANES;
D O I
10.1055/s-0033-1338806
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An approach toward the synthesis of N-heterocyclic anionic ionic liquids is described. The ionic liquids are readily obtained by the treatment of the sodium salt of the parent N-heterocycle with the halide salt of the desired cation. Good to excellent yields (62-99%) of the corresponding ionic liquids are obtained without the use of excessive materials and time associated with conventional methods for synthesizing heterocyclic based ionic liquids.
引用
收藏
页码:1428 / 1432
页数:5
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