VO2/TiN Plasmonic Thermochromic Smart Coatings for Room-Temperature Applications

被引:213
作者
Hao, Qi [1 ,2 ]
Li, Wan [1 ]
Xu, Huiyan [1 ,3 ]
Wang, Jiawei [2 ]
Yin, Yin [2 ]
Wang, Huaiyu [4 ]
Ma, Libo [2 ]
Ma, Fei [1 ,3 ]
Jiang, Xuchuan [5 ]
Schmidt, Oliver G. [2 ,6 ]
Chu, Paul K. [1 ]
机构
[1] City Univ Hong Kong, Dept Phys & Mat Sci, Tat Chee Ave, Kowloon 999077, Hong Kong, Peoples R China
[2] Leibniz IFW Dresden, Inst Integrat Nanosci, Helmholtzstr 20, D-01069 Dresden, Germany
[3] Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Shaanxi, Peoples R China
[4] Chinese Acad Sci, Ctr Biomed Mat & Interfaces, Shenzhen Inst Adv Technol, Shenzhen 518055, Peoples R China
[5] Monash Univ, Dept Chem Engn, Clayton, Vic 3800, Australia
[6] Tech Univ Chemnitz, Mat Syst Nanoelect, Reichenhainer Str 70, D-09107 Chemnitz, Germany
关键词
plasmonics; smart coatings; thermochromic; titanium nitride; vanadium dioxide; VO2; THIN-FILMS; TITANIUM NITRIDE NANOPARTICLES; METAL-INSULATOR-TRANSITION; PHASE-TRANSITION; REFRACTORY PLASMONICS; VANADIUM DIOXIDE; OPTICAL-PROPERTIES; NANOSTRUCTURES; NANOCRYSTALS; METAMATERIAL;
D O I
10.1002/adma.201705421
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Vanadium dioxide/titanium nitride (VO2/TiN) smart coatings are prepared by hybridizing thermochromic VO2 with plasmonic TiN nanoparticles. The VO2/TiN coatings can control infrared (IR) radiation dynamically in accordance with the ambient temperature and illumination intensity. It blocks IR light under strong illumination at 28 degrees C but is IR transparent under weak irradiation conditions or at a low temperature of 20 degrees C. The VO2/TiN coatings exhibit a good integral visible transmittance of up to 51% and excellent IR switching efficiency of 48% at 2000 nm. These unique advantages make VO2/TiN promising as smart energy-saving windows.
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页数:5
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