Preparation and luminescent properties of Tb3+ and Tb3+-Ce3+ doped Ba9Y2Si6O24 phosphors

被引:32
作者
Lee, Seul [1 ]
Park, Sangmoon [1 ]
机构
[1] Silla Univ, Dept Engn Energy & Appl Chem, Pusan 617736, South Korea
基金
新加坡国家研究基金会;
关键词
Orthosilicate; Phosphors; Cross-relaxation; Energy transfer; TUNABLE LUMINESCENCE; CROSS-RELAXATION; BA;
D O I
10.1016/j.jlumin.2013.05.008
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Luminescent materials composed of Ba9-3m/2TbmY2Si6O24 (m=0.005-0.6) were prepared via a solid-state reaction. The dependence of the luminescent intensity of the Tb3+-doped orthosilicates on the Tb3+ content (m=0.005-0.06) is also investigated. The photoluminescence properties of Tb3+ in Ba9-3m/2TbmY2Si6O24 orthosilicate phosphors were elucidated. Using these phosphors, the desired CIE values including emissions throughout the blue, blue-green, and green regions of the spectra were achieved. Co-doping Ce3+ into the Tb3+-doped host structure enabled a high-energy charge-transfer from Ce3+ to Tb3+; accordingly, the Tb3+-Ce3+-doped green phosphors will be useful for applications involving white-light near-UV light-emitting-diodes. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:215 / 218
页数:4
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