Nucleophilic CH functionalization of arenes: a contribution to green chemistry

被引：47
作者：
Charushin, V. N. [1 ,2 ]
Chupakhin, O. N. [1 ,2 ]
机构：
[1] Russian Acad Sci, Ural Branch, I Ya Postovsky Inst Organ Synth, 22 Ul S Kovalevskoy Akad Skaya, Ekaterinburg 620990, Russia
[2] Ural Fed Univ, 19 Ul Mira, Ekaterinburg 620002, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2019年 / 68卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
arenes; CH functionalization; PASE processes; nucleophilic aromatic substitution of hydrogen; oxidation of the sigma(H) adducts; elimination of auxiliary groups; catalytic CH activation; cross-coupling reactions; CH; CH cross-dehydrogenative coupling (CDC) reactions; catalytic dehydrogenation; anodic-oxidation; AROMATIC-SUBSTITUTION; H FUNCTIONALIZATION; OXIDATIVE ALKYLAMINATION; NITROAROMATIC EXPLOSIVES; N-OXIDES; HYDROGEN; S-N(H); PYRIMIDINES; AZAAROMATICS; METHODOLOGY;
D O I：
10.1007/s11172-019-2441-3
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The review is focused on premises, features and scope of the reactions leading to the direct functionalization of the CH bond in arenes by the action of nucleophiles. Practical importance and a contribution of synthetic approaches with minimal steps, the so called PASE- (pot-, atom-, and step-economic) processes, to green chemistry are also discussed.
引用
收藏
页码：453 / 471
页数：19
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