Formation of a 2D phase in the electrochemical reduction of 4,4′-bipyridine on mercury in the presence of iodide ions via a desorption-nucleation, reorientation-nucleation mechanisms

被引:5
作者
Gómez, L [1 ]
Ruiz, JJ [1 ]
Camacho, L [1 ]
Rodríguez-Amaro, R [1 ]
机构
[1] Univ Cordoba, Fac Ciencias, Dept Quim Fis & Termodinam Aplicada, E-14014 Cordoba, Spain
关键词
2D phase; 4,4 '-bipyridine; chronoamperometry;
D O I
10.1016/j.jelechem.2003.11.006
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
This paper reports new experimental evidence of the electrochemical formation of a 2D phase which, based on a recently developed model, takes place via a desorption-nucleation mechanism that includes the incorporation of adsorbed molecules into the condensed phase. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:179 / 183
页数:5
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