Studies on catalytic epoxidation reaction cycle with titanium silicalite-1 (TS-1) cluster model: TS-1 peroxide formation and epoxidation reaction

被引：2
|
作者：
Munakata, H [1 ]
Oumi, Y [1 ]
Miyamoto, A [1 ]
机构：
[1] Tohoku Univ, Grad Sch Engn, Dept Chem Mat, Aoba Ku, Sendai, Miyagi 9808579, Japan
来源：
SCIENCE AND TECHNOLOGY IN CATALYSIS 1998 | 1999年 / 121卷
关键词：
D O I：
10.1016/S0167-2991(99)80071-8
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
DFT calculations on TS-1 model clusters showed that activation of hydrogen peroxide on titanium silicalite-1 (TS-1) led to form a water adduct of peroxy TS-1 complex, which was examined as an oxidizing agent in the catalytic reaction cycle to produce epoxyethane from ethene.
引用
收藏
页码：227 / 232
页数：6
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