Synthesis, Characterization, and Crystal Structure of a New Supramolecular CdII Complex With Halogen-Substituted Salen-Type Bisoxime

被引：65

作者：

Sun, Yin-Xia ^{[1
]}

Zhang, Shou-Ting ^{[1
]}

Ren, Zong-Li ^{[1
]}

Dong, Xiu-Yan ^{[1
]}

Wang, Li ^{[1
]}

机构：

[1] Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Gansu, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2013年 / 43卷 / 08期

关键词：

Cd-II complex; crystal structure; halogen-substituted Salen-type bisoxime; supramolecular interaction; synthesis; SCHIFF-BASE COMPLEXES; MAGNETIC-PROPERTIES; SPECTROSCOPIC BEHAVIORS; ZINC(II) COMPLEX; LIGANDS; CU(II); TRINUCLEAR; CLUSTER; CO(II); PHENOLATE;

D O I：

10.1080/15533174.2012.753614

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new mononuclear Cd-II complex, [CdL(H2O)(2)], with halogen-substituted Salen-type bisoxime ligand (H2L = 4,4-dibromo- 6,6-dichloro-2,2-[ethylenedioxybis(nitrilomethylidyne)]diphenol), was synthesized and structurally characterized. The Cd-II complex crystallizes in the monoclinic system, space group C2/c. The Cd-II center exhibits a slightly distorted octahedral geometry with halogen-substituted Salen-type bisoxime ligand forming the basal N2O2 coordination plane and two oxygen atoms from the coordinated water molecules in the axial position. An infinite 1D metal-water chain is formed by intermolecular hydrogen-bonding and - stacking interactions of neighboring benzene rings. Supplemental materials are available for this article. Go to the publisher's online edition of Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry to view the supplemental file.

引用

页码：995 / 1000

页数：6

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