Vinylic substitution of chlorine in the reaction of 2,3,5,6-tetrachloro-1,4-benzoquinone with cyclohexylamine in acetonitrile solvent

被引：2

作者：

Dworniczak, M ^{[1
]}

机构：

[1] Adam Mickiewicz Univ Poznan, Fac Chem, PL-60780 Poznan, Poland

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 2001年 / 74卷 / 01期

关键词：

chloranil; cyclohexylamine; vinylic substitution; reaction mechanism;

D O I：

10.1023/A:1014151427865

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction of 2,3,5,6-tetrachloro-1,4-benzoquinone with cyclohexylamine in acetonitrile has been studied spectrophotometrically. The mechanism of the reaction is a concerted vinylic substitution of Cl atoms. Kinetics and activation parameters are reported.

引用

页码：67 / 70

页数：4

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