Sensitive and selective aggregation based colorimetric sensing of Fe3+ via interaction with acetyl salicylic acid derived gold nanoparticles

被引：43

作者：

Memon, Safia S. ^{[1
]}

Nafady, Ayman ^{[2
,3
]}

Solangi, Amber R. ^{[1
]}

Al-Enizi, Abdullah M. ^{[2
]}

Sirajuddin ^{[1
]}

Shah, Muhammad R. ^{[4
]}

Sherazi, Syed T. H. ^{[1
]}

Memon, Shabuddin ^{[1
]}

Arain, Munazza ^{[5
]}

Abro, Muhammad I. ^{[6
]}

Khattak, Manzoor I. ^{[7
]}

机构：

[1] Univ Sindh, Natl Ctr Excellence Analyt Chem, Jamshoro 76080, Pakistan

[2] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia

[3] Sohag Univ, Chem Dept, Fac Sci, Sohag 82524, Egypt

[4] Univ Karachi, HEJ Res Inst Chem, Int Ctr Chem & Biol Sci, Karachi 75270, Pakistan

[5] Univ Sindh, Dr MA Kazi Inst Chem, Jamshoro 76080, Pakistan

[6] Mehran Univ Engn & Technol, Depr Met & Mat Engn, Jamshoro, Pakistan

[7] Univ Balochistan, Dept Chem, Quetta, Pakistan

来源：

SENSORS AND ACTUATORS B-CHEMICAL | 2018年 / 259卷

关键词：

Acetyl salicylic acid; Gold nanoparticles; Iron; Colorimetric sensor; Water samples; SENSOR; IRON; CHEMOSENSOR; NANOSTRUCTURES; PIROXICAM; ELECTRODE;

D O I：

10.1016/j.snb.2017.12.162

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Here we highlight a single pot green synthetic protocol for gold nanoparticles (AuNps) using acetyl salicylic acid (ASA) drug as reducing and capping agent. These nanoparticles were characterized using UV-Vis (UV-Vis) spectroscopy, Fourier Transform Infrared (FT-IR) Spectroscopy, X-ray diffractometry (XRD) and Atomic Force Microscopy (AFM). The estimated average size of AuNps was 33 nm. These ASA-AuNps were employed to develop a highly selective and sensitive colorimetric sensor for Fe3+ detection. This sensor responded linearly to Fe3+ in the range of 0.3-2.1 mu mol L-1. The limit of detection (LOD) and limit of quantification (LOQ) of sensor was 0.051 and 0.17 mu mol L-1 respectively. The response of the developed sensor to the interfering ions like Ni2+, Hg2+, Cd2+, Cr3+, Co2+, As3+, Pb2+, Fe2+ and Zn2+ was negligible. The sensor was used successfully to detect Fe3+ in real water samples collected from various locations of the Sindh River. (c) 2017 Elsevier B.V. All rights reserved.

引用

页码：1006 / 1012

页数：7

共 25 条

[1] Rhodamine-hydroxamate-based fluorescent chemosensor for FeIII [J].