Direct synthesis and properties of monomeric and dimeric MnIII-salen complexes tuned by tetrahalocadmate anions

被引：4
|
作者：
Chygorin, Eduard M. [1 ]
Makhankova, Valeriya G. [1 ]
Ischenko, Mykola V. [1 ]
Kokozay, Vladimir N. [1 ]
Zubatyuk, Roman I. [2 ]
Shishkin, Oleg V. [2 ,3 ]
Jezierska, Julia [4 ]
机构：
[1] Taras Shevchenko Natl Univ Kyiv, Dept Inorgan Chem, UA-01601 Kiev, Ukraine
[2] Natl Acad Sci Ukraine, STC Inst Single Crystals, Div Funct Mat Chem, UA-61001 Kharkov, Ukraine
[3] Kharkov Natl Univ, Dept Inorgan Chem, UA-61077 Kharkov, Ukraine
[4] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 20卷
关键词：
Schiff base ligand; Cadmium; Manganese; X-ray crystallography; Antiferromagnetic interactions; SCHIFF-BASE COMPLEXES; MAGNETIC-PROPERTIES; MANGANESE(III) COMPLEXES; POLYNUCLEAR; LIGANDS;
D O I：
10.1016/j.inoche.2012.03.029
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two novel compounds [Mn(salen)(dmf)(2)](3)[Mn(salen)(dmf)(H2O)][CdCl4](2)center dot H2O (1) and ([Mn(salen)(CH3OH)](2)) [Mn(salen)(CH3OH)(2)](2)[Cdl(4)](2) (2) have been synthesised via interaction of manganese metal and cadmium halide with in situ generated salen ligand (salen = N,N'-ethylene-bis-salicylideneaminato) in non-aqueous (dmf, CH3OH) solutions. X-ray structure analysis reveals that in solid state 1 contains mononuclear M-III-salen species, whilst in 2 both monomeric and out-of-plane dimeric M-III-salen complexes are present. Moreover, in 2 the monomeric units are linked by H-bonds, forming other dimers. Equilibrium between monomeric and dimeric units in solutions of 1 and 2 was found by ESI mass-spectrometry. The magnetic measurements of 2 demonstrated antiferromagnetic interactions between Mn-III centres. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：282 / 285
页数：4
相关论文
共 50 条
  • [1] Self-assembly of dimeric MnIII-Schiff-Base complexes tuned by perchlorate anions
    Bermejo, Manuel R.
    Fernandez, M. Isabel
    Gomez-Forneas, Esther
    Gonzalez-Noya, Ana
    Maneiro, Marcelino
    Pedrido, Rosa
    Rodriguez, M. Jesu
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, 24 (24) : 3789 - 3797
  • [2] Catalysis of Enantioselective Strecker Reaction in the Synthesis of D-Homophenylalanine Using Recyclable, Chiral, Macrocyclic MnIII-Salen Complexes
    Saravanan, S.
    Khan, Noor-ul H.
    Bera, Prasanta K.
    Kureshy, Rukhsana I.
    Abdi, Sayed H. R.
    Kumari, Prathibha
    Bajaj, Hari C.
    CHEMCATCHEM, 2013, 5 (06) : 1374 - 1385
  • [3] Catalytic properties of a MnIII-salen complex immobilised in a pillared clay by simultaneous pillaring/encapsulation procedures
    Cardoso, B
    Pires, J
    Carvalho, AP
    Carvalho, MB
    Kuzniarska-Biernacka, I
    Silva, AR
    Freire, C
    de Castro, B
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (05) : 837 - 844
  • [4] Spin-Canted Antiferromagnetic Phase Transitions in Alternating Phenoxo- and Carboxylato-Bridged MnIII-Salen Complexes
    Kar, Paramita
    Guha, Pampa M.
    Drew, Michael G. B.
    Ishida, Takayuki
    Ghosh, Ashutosh
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2011, (13) : 2075 - 2085
  • [5] Supramolecular Dimeric MnIII Complexes: Synthesis, Structure, Magnetic Properties, and Catalytic Oxidation Studies
    Jana, Narayan Ch.
    Jaglicic, Zvonko
    Brandao, Paula
    Panja, Anangamohan
    ACS OMEGA, 2024, 9 (50): : 49953 - 49965
  • [6] Synthesis, crystal structures and magnetic properties of 1D polymeric [MnIII(salen)N3] and [MnIII(salen)Ag(CN)2] complexes
    Panja, A
    Shaikh, N
    Vojtísek, P
    Gao, S
    Banerjee, P
    NEW JOURNAL OF CHEMISTRY, 2002, 26 (08) : 1025 - 1028
  • [7] Fluorimetric Detection of Phosphates in Water Using a Disassembly Approach: A Comparison of FeIII-, ZnII-, MnII- and MnIII-salen Complexes
    Winkler, Daniela
    Banke, Sophie
    Kurz, Philipp
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2020, 646 (13): : 933 - 939
  • [8] 2D and 3D bimetallic oxalate-based ferromagnets prepared by insertion of MnIII-salen type complexes
    Clemente-Leon, Miguel
    Coronado, Eugenio
    Lopez-Jorda, Maurici
    DALTON TRANSACTIONS, 2013, 42 (14) : 5100 - 5110
  • [9] Synthesis, structure, and electronic properties of monomeric and dimeric trispyrazolylborate platinum(II) hydride complexes
    Reinartz, S
    Baik, MH
    White, PS
    Brookhart, M
    Templeton, JL
    INORGANIC CHEMISTRY, 2001, 40 (18) : 4726 - 4732
  • [10] Out-of-plane dimeric MnIII quadridentate Schiff-base complexes: Synthesis, structure and magnetic properties
    Feng, Yuhua
    Wang, Chao
    Zhao, Yafan
    Li, Jun
    Liao, Daizheng
    Yan, Shiping
    Wang, Qinglun
    INORGANICA CHIMICA ACTA, 2009, 362 (10) : 3563 - 3568
12345