Electrochemical reactions of layered niobate material as novel anode for sodium ion batteries

被引：20
作者：
Nakayama, Hideki [1 ]
Nose, Masafumi [1 ]
Nakanishi, Shinji [1 ]
Iba, Hideki [1 ]
机构：
[1] Toyota Motor Co Ltd, Battery Res Div, Susono, Shizuoka 4101193, Japan
来源：
JOURNAL OF POWER SOURCES | 2015年 / 287卷
关键词：
Sodium-ion battery; Anode material; Layered niobate; KNb3O8; INTERCALATION; NA; LITHIUM;
D O I：
10.1016/j.jpowsour.2015.04.048
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The electrochemical performances of layered niobium oxide materials were investigated for the first time as novel anode active materials for the sodium-ion battery. The layered niobate with the formula KNb3O8 was synthesized by a solid-state reaction and, has been evaluated as an anode electrode by a cyclic voltammetry technique and galvanostatic charge/discharge tests. The crystal structure of KNb3O8 contains the NbO6 octahedral units and potassium alkali-metal ions interlayer to form the layered structure. KNb3O8 has a redox reaction around 1 V vs. Na/Na+ and has a reversible capacity of 104 mAh/g corresponding to the 1.7 Na+ insertion/extraction in the KNb3O8 structure. The Nb K-edge X-ray absorption near edge structure (XANES) shows that the Nb oxidation state is converted from Nb5+ to Nb4+ during the Na+ insertion stage, and reversibly recovered to Nb5+ during the Na+ extraction stage. This is the first report that the layered niobate of KNb3O8 reversibly reacts with Na+ at the potential around 1 V vs. Na/Na+ via the Nb5+/4+ redox reaction. (C) 2015 Elsevier B.V. All rights reserved.
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收藏
页码：158 / 163
页数：6
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