Co-crystallisation of competing structural modes in geometrically constrained Jahn-Teller manganese(III) complexes

被引：10

作者：

Murray, Caroline ^{[1
,3
]}

Gildea, Brendan ^{[1
,3
]}

Mueller-Bunz, Helge ^{[1
,3
]}

Harding, Charles J. ^{[2
]}

Morgan, Grace G. ^{[1
,3
]}

机构：

[1] Univ Coll Dublin, Sch Chem & Chem Biol, Dublin 4, Ireland

[2] Open Univ, Dept Chem, Milton Keynes MK7 6AA, Bucks, England

[3] Univ Coll Dublin, SFI Strateg Res Cluster Solar Energy Convers, Dublin 4, Ireland

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 48期

关键词：

OXIDATION; STATES;

D O I：

10.1039/c2dt31742g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The combination of Jahn-Teller distortion and chelating ligands produces a fine balance between competing coordination modes in manganese(III) resulting in well-ordered co-crystallization of two distinct assemblies from one set of components under a single set of conditions.

引用

页码：14487 / 14489

页数：3

共 27 条

[1] DYNAMIC JAHN-TELLER EFFECT IN A MANGANESE(III) COMPLEX - SYNTHESIS AND STRUCTURE OF HEXAKIS(UREA)MANGANESE(III) PERCHLORATE [J].

AGHABOZORG, H ;

PALENIK, GJ ;

STOUFER, RC ;

SUMMERS, J .

INORGANIC CHEMISTRY, 1982, 21 (11) :3903-3907

[2] METAL-ASSISTED LIGAND OXIDATION - SYNTHESIS AND CHARACTERIZATION OF NOVEL MANGANESE(III), IRON(III), AND NICKEL(II) COMPLEXES [J].

ARULSAMY, N ;

HODGSON, DJ .

INORGANIC CHEMISTRY, 1994, 33 (20) :4531-4536

[3]

*BRUK AXS INC, 2000, SADABS

[4] New software for searching the Cambridge Structural Database and visualizing crystal structures [J].

Bruno, IJ ;

Cole, JC ;

Edgington, PR ;

Kessler, M ;

Macrae, CF ;

McCabe, P ;

Pearson, J ;

Taylor, R .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2002, 58 :389-397

[5]

Chatterji T, 2004, COLOSSAL MAGNETORESISTIVE MANGANITES, P321

[6] Mixed-valence manganites [J].

Coey, JMD ;

Viret, M ;

von Molnár, S .

ADVANCES IN PHYSICS, 1999, 48 (02) :167-293

[7] GEOMETRIC CONTROL OF MANGANESE REDOX STATE [J].

DREW, MGB ;

HARDING, CJ ;

MCKEE, V ;

MORGAN, GG ;

NELSON, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (10) :1035-1038

[8] Syntheses and characterization of three structure types for manganese(III) complexes with N,N′-ethylenebis(1-phenyl-3-imino-1-butanone) [J].

Feng, YL ;

Liu, SX .

JOURNAL OF COORDINATION CHEMISTRY, 1998, 44 (1-2) :81-90

[9] Manganese N-confused porphyrin reactivity: CH bond activation and meso carbon reduction [J].

Harvey, JD ;

Ziegler, CJ .

CHEMICAL COMMUNICATIONS, 2003, (23) :2890-2891

[10] Self-assembly of tetra- and hexanuclear circular helicates [J].

Hasenknopf, B ;

Lehn, JM ;

Boumediene, N ;

DupontGervais, A ;

VanDorsselaer, A ;

Kneisel, B ;

Fenske, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (45) :10956-10962

← 1 2 3 →