Hydrogen-Evolution Catalysts Based on Non-Noble Metal Nickel-Molybdenum Nitride Nanosheets

被引:1200
作者
Chen, Wei-Fu [1 ]
Sasaki, Kotaro [1 ]
Ma, Chao [2 ]
Frenkel, Anatoly I. [3 ]
Marinkovic, Nebojsa [4 ]
Muckerman, James T. [1 ]
Zhu, Yimei [2 ]
Adzic, Radoslav R. [1 ]
机构
[1] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA
[2] Brookhaven Natl Lab, Dept Sci, Upton, NY 11973 USA
[3] Yeshiva Univ, Dept Phys, New York, NY 10016 USA
[4] Univ Delaware, Dept Chem Engn, Newark, DE 19716 USA
关键词
electrochemistry; evolution of hydrogen; heterogeneous catalysis; metal nitrides; nanosheets; NI; HYDRODENITROGENATION; HYDRODESULFURIZATION; ELECTROCATALYSTS; SEGREGATION; MORPHOLOGY; SYNERGISM; CATHODES; CARBIDES; ALLOYS;
D O I
10.1002/anie.201200699
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Not noble but effective: A new class of heterogeneous hydrogen-evolving electrocatalysts based on inexpensive components was developed. The carbon-supported nickel-molybdenum nitride (NiMoN x, see picture) catalyst had a nanoscale sheet structure comprising a few layers and an abundance of highly accessible reactive sites. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:6131 / 6135
页数:5
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