Hydrogen-Evolution Catalysts Based on Non-Noble Metal Nickel-Molybdenum Nitride Nanosheets

被引：1217

作者：

Chen, Wei-Fu ^{[1
]}

Sasaki, Kotaro ^{[1
]}

Ma, Chao ^{[2
]}

Frenkel, Anatoly I. ^{[3
]}

Marinkovic, Nebojsa ^{[4
]}

Muckerman, James T. ^{[1
]}

Zhu, Yimei ^{[2
]}

Adzic, Radoslav R. ^{[1
]}

机构：

[1] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA

[2] Brookhaven Natl Lab, Dept Sci, Upton, NY 11973 USA

[3] Yeshiva Univ, Dept Phys, New York, NY 10016 USA

[4] Univ Delaware, Dept Chem Engn, Newark, DE 19716 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 25期

关键词：

electrochemistry; evolution of hydrogen; heterogeneous catalysis; metal nitrides; nanosheets; NI; HYDRODENITROGENATION; HYDRODESULFURIZATION; ELECTROCATALYSTS; SEGREGATION; MORPHOLOGY; SYNERGISM; CATHODES; CARBIDES; ALLOYS;

D O I：

10.1002/anie.201200699

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Not noble but effective: A new class of heterogeneous hydrogen-evolving electrocatalysts based on inexpensive components was developed. The carbon-supported nickel-molybdenum nitride (NiMoN x, see picture) catalyst had a nanoscale sheet structure comprising a few layers and an abundance of highly accessible reactive sites. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

收藏

页码：6131 / 6135

页数：5

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