Mossbauer and electrical studies of NixCo1-xFe2O4 nanoparticles

Nanocrystalline nickel substituted cobalt spinel ferrites with chemical formula NixCo1-xFe2O4 (0 <= x <= 1.0) have been synthesized by the glycol-thermal technique under low reaction temperature of 200 degrees C. The crystallite size ranges from about 8 nm to 14 nm across the composition range. Strong correlation between particle size and sample reaction pressure has been observed. This shows dependence of the magnetic properties on the synthesis conditions. Fe-57 Mossbauer spectra recorded at room temperature (similar to 300 K) show ferrimagnetic behaviour of the compounds and have been explained on the bases of composition and crystallite size. Mossbauer data recorded at 80 K are indicative of enhanced hyperfine fields and isomer shifts due to increased magnetic order. Magnetization results reveal superparamagnetic nature of the compounds investigated. Resistivity measurements on the pellet samples annealed at 1100 degrees C show evidence of semiconducting behaviour. The current results also show significant differences in the resistivity determined from each face of a pellet. (C) 2018 Elsevier B.V. All rights reserved.