Synthesis and crystal structure of {Ru2(CO)6-μ2-η3-[(Ph)C-C(H)-C(H)-N=C(H)-C(H)=C(H)(Ph)]} - The first structurally characterized iminoallyl ruthenium carbonyl complex

被引：0

作者：

Biletzki, Tobias ^{[1
]}

Goerls, Helmar ^{[2
]}

Imhof, Wolfgang ^{[1
]}

机构：

[1] Univ Koblenz Landau, Inst Integrated Nat Sci, D-56070 Koblenz, Germany

[2] Univ Jena, Inst Inorgan & Analyt Chem, D-07743 Jena, Germany

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 30卷

关键词：

Ruthenium; C-H activation; Catalysis; X-ray; ONE-POT SYNTHESIS; C-BOND FORMATION; ALPHA; BETA-UNSATURATED IMINES; CATALYTIC FORMATION; GAMMA-LACTAMS; H ACTIVATION; CHEMOSELECTIVITY; CYCLOADDITION; DERIVATIVES; MONOXIDE;

D O I：

10.1016/j.inoche.2013.01.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dinuclear ruthenium carbonyl cluster {Ru-2(CO)(6)-mu(2)-eta(3)-[(Ph)C-C(H)-C(H)-N=C(H)-C(H)=C(H)(Ph)]} is produced from the reaction of cinnamaldehyde and Ru-3(CO)(12) in a 2.0 M solution of ammonia in ethanol. From the crystal structure it gets obvious that ammonia reacted with two molecules of cinnamaldehyde. The resulting ligand may best be described as a formally dianionic ruthenium coordinated imino-allyl-system with one exocyclic 3-phenylallylidene unit that shows no interaction with the transition metals whereas the second one is bound to ruthenium via a C-H activation step in gamma-position with respect to the nitrogen atom. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：62 / 64

页数：3

共 24 条

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