Synthesis, conformational behavior, and basicity of new pyridine-bridged calix[6]arenes

被引：0

作者：

Ross, H ^{[1
]}

Luning, U ^{[1
]}

机构：

[1] CHRISTIAN ALBRECHTS UNIV KIEL,INST ORGAN CHEM,D-24109 KIEL,GERMANY

来源：

LIEBIGS ANNALEN | 1996年 / 09期

关键词：

calixarenes; concave reagents; pyridines;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Compounds 2-6 were synthesized by starting from the pyridine-bridged calix[6]arenes 1. Most of these derivatives exist in a concave conformation like their parent compounds 1, but in some cases the conformational behavior is different. Relative basicities of 1-6 and of the open-chain model compounds 7 were measured by a photometrical titration against thymol blue. An unexpectedly high basicity of 1-4 was found.

引用

页码：1367 / 1373

页数：7

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