A host-guest hybrid framework with Anderson anions as template: synthesis, crystal structure and photocatalytic properties

被引：34

作者：

Chen, Hao ^{[1
]}

An, Haiyan ^{[1
]}

Liu, Xuan ^{[1
]}

Wang, Huilong ^{[1
]}

Chen, Zhaofei ^{[1
]}

Zhang, Hua ^{[1
]}

Hu, Ying ^{[1
]}

机构：

[1] Dalian Univ Technol, Coll Chem, Dalian 116023, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 21卷

基金：

中国国家自然科学基金;

关键词：

Host-guest compound; Anderson-anion template; Photocatalytic properties; METAL-ORGANIC FRAMEWORK; COORDINATION POLYMERS; CHANNELS; CONSTRUCTION; CATALYSIS; UNITS;

D O I：

10.1016/j.inoche.2012.04.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new Anderson-anion-templated inorganic-organic hybrid compound, H[(bitdc)Ni(H2O)(3)](2)[IMo6O24]center dot 6H(2)O (1) (bitdc = N,N'-bis(isonicotinoyl)-trans-1,2-diaminocyclohexane), has been synthesized and characterized by elemental analysis, IR spectroscopy, TG analysis, Powder XRD and single-crystal X-ray diffraction. Compound 1 is made up of Anderson-type polyoxoanions [IMo6O24](5-) and dinuclear [(bitdc)(2)Ni-2(H2O)(6)](4+) coordination complexes to yield an intriguing 3D supramolecular host-guest structure. To our best knowledge, compound 1 represents the first example of host-guest compounds with Anderson anions as template. The photocatalytic properties and magnetic properties of 1 have been investigated. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：65 / 68

页数：4

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