CONVERSION OF FRUCTOSE TO 5-HYDROXYMETHYL-FURFURAL WITH A FUNCTIONALIZED IONIC LIQUID

被引：0

作者：

Ma, Hao ^{[3
]}

Zhou, Bo ^{[3
]}

Li, Yiqun ^{[3
]}

Argyropoulos, Dimitris S. ^{[1
,2
]}

机构：

[1] N Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USA

[2] Univ Helsinki, Dept Chem, Helsinki 00014, Finland

[3] Jinan Univ, Dept Chem, Guangzhou 510632, Guangdong, Peoples R China

来源：

BIORESOURCES | 2012年 / 7卷 / 01期

基金：

中国国家自然科学基金;

关键词：

D-Fructose; 5-Hydroxymethylfurfural; 1-(2-Chloroethyl)-3-methylimidazolium chloride; Catalytic conversion; Ionic liquid; BIOMASS; ACID; EFFICIENT; FUELS; TRANSFORMATION; DEHYDRATION; DISSOLUTION; CHEMISTRY; CATALYSTS; CELLULOSE;

D O I：

暂无

中图分类号：

TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];

学科分类号：

0805 ; 080502 ; 0822 ;

摘要：

Fructose can be efficiently converted to 5-hydroxymethylfurfural by using the functionalized ionic liquid 3-(2-chloroethyl)-1-methylimidazolium chloride as both solvent and catalyst in the presence of water. This work advances the field and is distinct from earlier efforts in the sense that the observed yields of HMF from fructose are rather high and the reaction conditions rather mild and neutral in the complete absence of acidic additives (HMF yield 76% at 100 degrees C in 40 minutes).

引用

页码：533 / 544

页数：12

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