Synthesis of graphene oxide sheets decorated by silver nanoparticles in organic phase and their catalytic activity

被引:74
作者
Mao, Aiqin [1 ,2 ]
Zhang, Danhui [1 ,3 ]
Jin, Xia [2 ]
Gu, Xiaolong [2 ]
Wei, Xiaoqing [1 ]
Yang, Guojing [1 ]
Liu, Xiaoheng [3 ]
机构
[1] Anhui Univ Technol, Sch Mat Sci & Engn, Anhui Key Lab Met Mat & Proc, Maanshan 243002, Anhui, Peoples R China
[2] Zhejiang Prov Key Lab Soldering & Brazing Mat & T, Hangzhou, Zhejiang, Peoples R China
[3] Nanjing Univ Sci & Technol, Educ Minist Soft Chem & Funct Mat, Key Lab, Nanjing 210094, Jiangsu, Peoples R China
关键词
Inorganic compounds; Metals; Nanostructures; Chemical synthesis; X-ray diffraction; COMPOSITE FILMS;
D O I
10.1016/j.jpcs.2012.03.013
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The graphene oxide(GO) sheets decorated by Ag nanoparticles were prepared using a liquid-liquid two-phase method at the room temperature. The synthesized samples existed in the organic phase and were characterized by X-ray diffraction, transmission electron microscopy, UV-vis spectroscopy and Raman spectra. The results demonstrate that these silver-nanoparticles with diameter of about 10 nm assembled on graphene oxide sheets are flexible and can form stable suspensions in organic phase. Raman signals of graphene oxide sheets are increased by the attached silver nanoparticles, displaying higher surface-enhanced Raman scattering activity. Furthermore, Ag/GO are found to serve as effective catalysts to activate the reduction of 4-nitrophenol (4NP) in the presence of NaBH4. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:982 / 986
页数:5
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