Control of triboelectric charges on common polymers by photoexcitation of organic dyes

被引:30
作者
Cezan, S. Doruk [1 ]
Nalbant, Atakan A. [1 ]
Buyuktemiz, Muhammed [2 ]
Dede, Yavuz [2 ]
Baytekin, H. Tarik [3 ]
Baytekin, Bilge [1 ,3 ]
机构
[1] Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey
[2] Gazi Univ, Dept Chem, Fac Sci, TR-06500 Ankara, Turkey
[3] Bilkent Univ, UNAM Natl Nanotechnol Res Ctr, TR-06800 Ankara, Turkey
基金
欧盟地平线“2020”;
关键词
CONTACT ELECTRIFICATION; SURFACE; MECHANORADICALS; ACTIVATION; SEPARATION; RADICALS;
D O I
10.1038/s41467-018-08037-5
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Triboelectric charging of insulators, also known as contact charging in which electrical charges develop on surfaces upon contact, is a significant problem that is especially critical for various industries such as polymers, pharmaceuticals, electronics, and space. Several methods of tribocharge mitigation exist in practice; however, none can reach the practicality of using light in the process. Here we show a light-controlled manipulation of triboelectric charges on common polymers, in which the tribocharges are mitigated upon illumination with appropriate wavelengths of light in presence of a mediator organic dye. Our method provides spatial and temporal control of mitigation of static charges on common polymer surfaces by a mechanism that involves photoexcitation of organic dyes, which also allows additional control using wavelength. This control over charge mitigation provides a way to manipulate macroscopic objects by tribocharging followed by light-controlled discharging.
引用
收藏
页数:8
相关论文
共 30 条
[1]   Conducting polymers in microelectronics [J].
Angelopoulos, M .
IBM JOURNAL OF RESEARCH AND DEVELOPMENT, 2001, 45 (01) :57-75
[2]   Mechanically Driven Activation of Polyaniline into Its Conductive Form [J].
Baytekin, Bilge ;
Baytekin, H. Tarik ;
Grzybowski, Bartosz A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (27) :6946-6950
[3]   What Really Drives Chemical Reactions on Contact Charged Surfaces? [J].
Baytekin, Bilge ;
Baytekin, H. Tarik ;
Grzybowski, Bartosz A. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (17) :7223-7226
[4]   The Mosaic of Surface Charge in Contact Electrification [J].
Baytekin, H. T. ;
Patashinski, A. Z. ;
Branicki, M. ;
Baytekin, B. ;
Soh, S. ;
Grzybowski, B. A. .
SCIENCE, 2011, 333 (6040) :308-312
[5]   Control of Surface Charges by Radicals as a Principle of Antistatic Polymers Protecting Electronic Circuitry [J].
Baytekin, H. Tarik ;
Baytekin, Bilge ;
Hermans, Thomas M. ;
Kowalczyk, Bartlomiej ;
Grzybowski, Bartosz A. .
SCIENCE, 2013, 341 (6152) :1368-1371
[6]   Material Transfer and Polarity Reversal in Contact Charging [J].
Baytekin, H. Tarik ;
Baytekin, Bilge ;
Incorvati, Jared T. ;
Grzybowski, Bartosz A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (20) :4843-4847
[7]   Mechanoradicals Created in "Polymeric Sponges" Drive Reactions in Aqueous Media [J].
Baytekin, H. Tarik ;
Baytekin, Bilge ;
Grzybowski, Bartosz A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (15) :3596-3600
[8]   Is Water Necessary for Contact Electrification? [J].
Baytekin, H. Tarik ;
Baytekin, Bilge ;
Soh, Siowling ;
Grzybowski, Bartosz A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (30) :6766-6770
[9]   Mechanochemistry: The mechanical activation of covalent bonds [J].
Beyer, MK ;
Clausen-Schaumann, H .
CHEMICAL REVIEWS, 2005, 105 (08) :2921-2948
[10]   Triboelectricity: Macroscopic Charge Patterns Formed by Self-Arraying Ions on Polymer Surfaces [J].
Burgo, Thiago A. L. ;
Ducati, Telma R. D. ;
Francisco, Kelly R. ;
Clinckspoor, Karl J. ;
Galembeck, Fernando ;
Galembeck, Sergio E. .
LANGMUIR, 2012, 28 (19) :7407-7416