Cubatic phase for tetrapods

被引:28
作者
Blaak, R
Mulder, BM
Frenkel, D
机构
[1] Univ Dusseldorf, Inst Theoret Phys 2, D-40225 Dusseldorf, Germany
[2] FOM, Inst Atom & Mol Phys, NL-1098 SJ Amsterdam, Netherlands
关键词
D O I
10.1063/1.1649733
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We investigate the phase behavior of tetrapods, hard nonconvex bodies formed by four rods connected under tetrahedral angles. We predict that, depending on the relative lengths of the rods these particles can form a uniaxial nematic phase, and more surprisingly they can exhibit a cubatic phase, a special case of the biaxial nematic phase. These predictions may be experimentally testable, as experimental realizations of tetrapods have recently become available. (C) 2004 American Institute of Physics.
引用
收藏
页码:5486 / 5492
页数:7
相关论文
共 16 条
[1]   LIQUID-CRYSTAL PHASE-TRANSITIONS IN MIXTURES OF RODLIKE AND PLATELIKE MOLECULES [J].
ALBEN, R .
JOURNAL OF CHEMICAL PHYSICS, 1973, 59 (08) :4299-4304
[2]   Phase diagram of Onsager crosses [J].
Blaak, R ;
Mulder, BM .
PHYSICAL REVIEW E, 1998, 58 (05) :5873-5884
[3]  
Blaak R, 1998, MOL PHYS, V94, P401, DOI 10.1080/00268979809482331
[4]  
Brink D.M., 1968, Angular Momentum, V2nd
[5]   Demixing in hard ellipsoid rod-plate mixtures [J].
Camp, PJ ;
Allen, MP ;
Bolhuis, PG ;
Frenkel, D .
JOURNAL OF CHEMICAL PHYSICS, 1997, 106 (22) :9270-9275
[6]   ORDERED STATES OF A NEMATIC LIQUID [J].
FREISER, MJ .
PHYSICAL REVIEW LETTERS, 1970, 24 (19) :1041-&
[7]  
FRENKEL D, 1988, J PHYS CHEM-US, V92, P5314
[8]  
FRENKEL D, 1991, LES HOUCH S, V51, P689
[9]   ONSAGER SPHEROCYLINDERS REVISITED [J].
FRENKEL, D .
JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (19) :4912-4916
[10]  
Gradshteyn I. S., 2000, TABLE INTEGRALS SERI