Glycosyl triflates, which serve as important intermediates in glycosylation reactions, were generated and accumulated by low-temperature electrochemical oxidation of thioglycosides, such as thioglucosides, thiogalacto-sides, and thiomannosides, in the presence of tetrabutylammonium triflate (Bu4NOTf) as a supporting electrolyte. The solutions of glycosyl triflates thus obtained were then characterized by low-temperature NMR measurements. The thermal stability of glycosyl triflates and their reactions with glycosyl acceptors were also studied.
机构:
Cent Drug Res Inst, Med & Proc Chem Div, Lucknow 226001, Uttar Pradesh, IndiaCent Drug Res Inst, Med & Proc Chem Div, Lucknow 226001, Uttar Pradesh, India
Agnihotri, G
Misra, AK
论文数: 0引用数: 0
h-index: 0
机构:
Cent Drug Res Inst, Med & Proc Chem Div, Lucknow 226001, Uttar Pradesh, IndiaCent Drug Res Inst, Med & Proc Chem Div, Lucknow 226001, Uttar Pradesh, India
机构:
Hokkaido Univ, Grad Sch Engn, Div Mol Chem, Organ Synth Lab, Sapporo, Hokkaido 0608628, JapanHokkaido Univ, Grad Sch Engn, Div Mol Chem, Organ Synth Lab, Sapporo, Hokkaido 0608628, Japan
Kanaya, H
Fujimura, Y
论文数: 0引用数: 0
h-index: 0
机构:
Hokkaido Univ, Grad Sch Engn, Div Mol Chem, Organ Synth Lab, Sapporo, Hokkaido 0608628, JapanHokkaido Univ, Grad Sch Engn, Div Mol Chem, Organ Synth Lab, Sapporo, Hokkaido 0608628, Japan
Fujimura, Y
Tokuda, M
论文数: 0引用数: 0
h-index: 0
机构:
Hokkaido Univ, Grad Sch Engn, Div Mol Chem, Organ Synth Lab, Sapporo, Hokkaido 0608628, JapanHokkaido Univ, Grad Sch Engn, Div Mol Chem, Organ Synth Lab, Sapporo, Hokkaido 0608628, Japan