Comparative Studies of the Corrosion Inhibition Efficacy of a Dicationic Monomer and Its Polymer against API X60 Steel Corrosion in Simulated Acidizing Fluid under Static and Hydrodynamic Conditions

被引:39
作者
Odewunmi, Nurudeen A. [1 ]
Solomon, Moses M. [2 ]
Umoren, Saviour A. [2 ]
Ali, Shaikh A. [1 ]
机构
[1] King Fahd Univ Petr & Minerals, Ctr Res Excellence Corros, Res Inst, Dhahran 31261, Saudi Arabia
[2] King Fahd Univ Petr & Minerals, Dept Chem, Dhahran 31261, Saudi Arabia
来源
ACS OMEGA | 2020年 / 5卷 / 42期
关键词
MILD-STEEL; ADSORPTION BEHAVIOR; ANTICORROSION PROPERTY; SCHIFF-BASES; ACID; HCL; ENVIRONMENT; SURFACE; IODIDE; MEDIA;
D O I
10.1021/acsomega.0c02345
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
N-1,N-1-diallyi-N-6,N-6,N-6-tripropylhexane-1,6-diaminium chloride (NDTHDC) and its polymer poly(N-1,N-1-diallyl-N-6,N-6,N-6-tripropylhexane-1,6-diaminium chloride) (poly-NDTHDC) were synthesized and tested against API X60 carbon steel corrosion in 15 wt % HCl solution. Weight loss, electrochemical, and surface analysis techniques were used. Results show that poly-NDTHDC is better than NDTHDC. Moreover, 1000 mg/L NDTHDC protected the studied surface by 79.1% at 25 degrees C, while 100 mg/L poly-NDTHDC afforded 86.1% protection. Inhibition efficiency increases with temperature (up to 60 degrees C) but depreciates thereafter. NDTHDC and poly-NDTHDC perform better under the hydrodynamic condition than the static condition. TGA and FTIR results reveal that poly-NDTHDC is chemically and thermally stable.
引用
收藏
页码:27057 / 27071
页数:15
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