Synthesis of vinca alkaloids and related compounds .79. An intriguing retro Diels-Alder reaction

被引：5

作者：

Szantay, C ^{[1
]}

Moldvai, I ^{[1
]}

Tarkanyi, G ^{[1
]}

Szantay, C ^{[1
]}

机构：

[1] HUNGARIAN ACAD SCI,CENT RES INST CHEM,H-1525 BUDAPEST,HUNGARY

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1996年 / 61卷 / 09期

关键词：

D O I：

10.1021/jo9521110

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The dimerization production of criocerine (1) are different (2 or 3) depending on whether the reaction is carried out in acetic acid or trifluoroacetic acid. The highly strained product 3 rearranges spontaneously through a retro Diels-Alder reaction. All structures involved were thoroughly investigated by NMR spectroscopic methods.

引用

页码：2946 / 2950

页数：5

共 9 条

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