Hollow TiO2 nanocages with rubik-like structure for high-performance photocatalysts

被引:18
作者
Jiang, Guohua [1 ,2 ]
Wang, Xiaohong [1 ,2 ]
Zhou, Yang [2 ]
Wang, Rijing [1 ,2 ]
Hu, Ruanbing [1 ,2 ]
Xi, Xiaoguang [1 ,2 ]
Chen, Wenxing [1 ,2 ]
机构
[1] Zhejiang Sci Tech Univ, Key Lab Adv Text Mat & Mfg Technol ATMT, Minist Educ, Hangzhou 310018, Zhejiang, Peoples R China
[2] Zhejiang Sci Tech Univ, Dept Mat Engn, Coll Mat & Text, Hangzhou 310018, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
Nanoparticles; Deposition; Nanocomposites; Photo-catalysis; Degradation; MICROSPHERES; SPHERES; OXIDE;
D O I
10.1016/j.matlet.2012.08.092
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Hollow TiO2 nanocages with rubik-like structure were synthesized via a combined hydrolysis/hydrothermal method. Firstly, highly uniform Cu2O nanocubes covered by TiO2 layer were prepared by hydrothermal hydrolysis of (NH4)(2)TiF6 following by reducing copper-citrate complex with ascorbic acid. The Cu2O core templates could be easily removed in dilute HCl solution to form a hollow rubik-like structure. The obtained TiO2 nanocages show promising efficiency in the photocatalytic degradation of phenol pollutions. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:59 / 62
页数:4
相关论文
共 17 条
[1]   Synthesis and biomedical applications of hollow nanostructures [J].
An, Kwangjin ;
Hyeon, Taeghwan .
NANO TODAY, 2009, 4 (04) :359-373
[2]   The shape-specific photocatalytic efficiency of quantum size TiO2 nanoparticles [J].
Chen, Zheng ;
Liu, Jinghai ;
Qiu, Song ;
Dawson, Graham ;
Chen, Wei .
CATALYSIS COMMUNICATIONS, 2012, 21 :1-4
[3]   Photo-degradation of methylene blue by multi-walled carbon nanotubes/TiO2 composites [J].
Jiang, Guohua ;
Zheng, Xiaoyan ;
Wang, Yin ;
Li, Tianwen ;
Sun, Xinke .
POWDER TECHNOLOGY, 2011, 207 (1-3) :465-469
[4]   Fabrication of Spherical Multi-Hollow TiO2 Nanostructures for Photoanode Film with Enhanced Light-Scattering Performance [J].
Jiang, Jun ;
Gu, Feng ;
Shao, Wei ;
Li, Chunzhong .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (07) :2838-2845
[5]   A one-pot synthetic approach to prepare palladium nanoparticles embedded hierarchically porous TiO2 hollow spheres for hydrogen peroxide sensing [J].
Kong, Lirong ;
Lu, Xiaofeng ;
Bian, Xiujie ;
Zhang, Wanjin ;
Wang, Ce .
JOURNAL OF SOLID STATE CHEMISTRY, 2010, 183 (10) :2421-2425
[6]   Cu2O/Cu/TiO2 nanotube Ohmic heterojunction arrays with enhanced photocatalytic hydrogen production activity [J].
Li, Zhonghua ;
Liu, Jiawen ;
Wang, Dongjun ;
Gao, Yuan ;
Shen, Jun .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (08) :6431-6437
[7]   Embossed TiO2 Thin Films with Tailored Links between Hollow Hemispheres: Synthesis and Gas-Sensing Properties [J].
Moon, Hi Gyu ;
Shim, Young-Seok ;
Su, Dong ;
Park, Hyung-Ho ;
Yoon, Seok-Jin ;
Jang, Ho Won .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (20) :9993-9999
[8]   Hollow anatase TiO2 porous microspheres with V-shaped channels and exposed (101) facets: Anisotropic etching and photovoltaic properties [J].
Pan, Hao ;
Qian, Jieshu ;
Cui, Yuming ;
Xie, Haixian ;
Zhou, Xingfu .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (13) :6002-6009
[9]   Grain boundary layers in nanocrystalline ferromagnetic zinc oxide [J].
Straumal, B. B. ;
Myatiev, A. A. ;
Straumal, P. B. ;
Mazilkin, A. A. ;
Protasova, S. G. ;
Goering, E. ;
Baretzky, B. .
JETP LETTERS, 2010, 92 (06) :396-400
[10]   Ferromagnetic properties of the Mn-doped nanograined ZnO films [J].
Straumal, B. B. ;
Protasova, S. G. ;
Mazilkin, A. A. ;
Myatiev, A. A. ;
Straumal, P. B. ;
Schuetz, G. ;
Goering, E. ;
Baretzky, B. .
JOURNAL OF APPLIED PHYSICS, 2010, 108 (07)