Corrosion-resistant hybrid coatings based on graphene oxide-zirconia dioxide/epoxy system

被引:81
作者
Di, Haihui [1 ,2 ]
Yu, Zongxue [1 ,2 ]
Ma, Yu [3 ]
Zhang, Chunli [1 ,2 ]
Li, Fei [1 ,2 ]
Lv, Liang [1 ,2 ]
Pan, Yang [1 ,2 ]
Shi, Heng [1 ,2 ]
He, Yi [1 ,2 ]
机构
[1] Southwest Petr Univ, Sch Chem & Chem Engn, Chengdu 610500, Peoples R China
[2] Oil & Gas Field Appl Chem Key Lab Sichuan Prov, Chengdu 610500, Peoples R China
[3] Xinzhu Rd & Bridge Machinery Co Ltd, Dept Rail & Track, Chengdu 611400, Peoples R China
关键词
Graphene oxide; Zirconia dioxide; Epoxy; Corrosion protection; MECHANICAL-PROPERTIES; EPOXY NANOCOMPOSITES; MILD-STEEL; COMPOSITES; NANOPARTICLES; PERFORMANCE; PROTECTION; BARRIER; FUNCTIONALIZATION; STRENGTH;
D O I
10.1016/j.jtice.2016.08.008
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The hybrid coatings based on graphene oxide-zirconia dioxide/epoxy (GO-ZrO2/EP) system were fabricated and applied for corrosion protection of metal substrate. First, GO-ZrO2 hybrid was synthesized through two different silane coupling agents and the morphology and structure were confirmed by Field emission scanning electron microscope (FE-SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) analysis. Then, GO-ZrO2 was incorporated into EP to investigate the corrosion protection of metal substrate. Investigations revealed that the corrosion protective properties were significantly enhanced by the addition of GO-ZrO2 to EP. The enhancement attributed to the sheet like structure, uniform dispersion and exfoliation of GO-ZrO2 hybrid within EP matrix, which effectively prevented the underlying metal substrate from corrosion attack. (C) 2016 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:511 / 520
页数:10
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