Flexible supercapacitor electrodes using metal-organic frameworks

被引:115
作者
Cherusseri, Jayesh [1 ]
Pandey, Deepak [1 ,2 ]
Kumar, Kowsik Sambath [1 ,2 ]
Thomas, Jayan [1 ,2 ,3 ]
Zhai, Lei [1 ,2 ,4 ]
机构
[1] Univ Cent Florida, Nanosci Technol Ctr, Orlando, FL 32826 USA
[2] Univ Cent Florida, Mat Sci & Engn, Orlando, FL 32816 USA
[3] Univ Cent Florida, Coll Opt & Pholon, Orlando, FL 32816 USA
[4] Univ Cent Florida, Dept Chem, Orlando, FL 32816 USA
关键词
SOLID-STATE SUPERCAPACITOR; HIGH-PERFORMANCE; POROUS CARBON; ENERGY-STORAGE; ASYMMETRIC SUPERCAPACITORS; HYDROTHERMAL SYNTHESIS; NANOPOROUS CARBON; MOF; COMPOSITES; GRAPHENE;
D O I
10.1039/d0nr03549a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Advancements in the field of flexible and wearable devices require flexible energy storage devices to cater their power demands. Metal-ion batteries (such as lithium-ion batteries, sodium-ion batteries,etc.) and electrochemical capacitors (also called supercapacitors or ultracapacitors) have achieved great interest in the recent past due to their superior energy storage characteristics like high power density and long cycle life. A major bottleneck of using metal-ion batteries in wearable devices is their lack of flexibility. Low power density, toxicity and flammability due to organic electrolytes inhibit them from safe on-body device applications. On the other hand, supercapacitors can be made with aqueous electrolytes, making them a safer alternative for wearable applications. Metal-organic frameworks (MOFs) are novel candidates as electrode materials due to their salient features such as large surface area, three-dimensional porous architecture, permeability to foreign entities, structural tailorability,etc. Though pristine MOFs suffer from poor intrinsic conductivity, this can be rectified by preparing composites with other electronically conducting materials. MOF-based electrodes are highly promising for flexible and wearable supercapacitors since they exhibit good energy and power densities. This review focuses on the new developments in the field of MOF-based composite electrodes for developing flexible supercapacitors.
引用
收藏
页码:17649 / 17662
页数:14
相关论文
共 105 条
[1]   Synthesis, size and structural evolution of metal-organic framework-199 via a reaction-diffusion process at room temperature [J].
Al-Ghoul, Mazen ;
Issa, Razan ;
Hmadeh, Mohamad .
CRYSTENGCOMM, 2017, 19 (04) :608-612
[2]   Review of PVA-based gel polymer electrolytes in flexible solid-state supercapacitors: Opportunities and challenges [J].
Alipoori, Saeideh ;
Mazinani, Saeedeh ;
Aboutalebi, Seyed Hamed ;
Sharif, Farhad .
JOURNAL OF ENERGY STORAGE, 2020, 27
[3]  
[Anonymous], 2014, ANGEW CHEM INT EDIT, DOI [DOI 10.1002/anie.201710599, DOI 10.1002/anie.201308013]
[4]   MOF-derived crumpled-sheet-assembled perforated carbon cuboids as highly effective cathode active materials for ultra-high energy density Li-ion hybrid electrochemical capacitors (Li-HECs) [J].
Banerjee, Abhik ;
Upadhyay, Kush Kumar ;
Puthusseri, Dhanya ;
Aravindan, Vanchiappan ;
Madhavi, Srinivasan ;
Ogale, Satishchandra .
NANOSCALE, 2014, 6 (08) :4387-4394
[5]   The Development and Future of Lithium Ion Batteries [J].
Blomgren, George E. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2017, 164 (01) :A5019-A5025
[6]   Luminescent terbium-containing metal-organic framework films: new approaches for the electrochemical synthesis and application as detectors for explosives [J].
Campagnol, Nicolo ;
Souza, Ernesto Rezende ;
De Vos, Dirk E. ;
Binnemans, Koen ;
Fransaer, Jan .
CHEMICAL COMMUNICATIONS, 2014, 50 (83) :12545-12547
[7]   A Hybrid Supercapacitor based on Porous Carbon and the Metal-Organic Framework MIL-100(Fe) [J].
Campagnol, Nicolo ;
Romero-Vara, Ricardo ;
Deleu, Willem ;
Stappers, Linda ;
Binnemans, Koen ;
De Vos, Dirk E. ;
Fransaer, Jan .
CHEMELECTROCHEM, 2014, 1 (07) :1182-1188
[8]   MOF-derived sponge-like hierarchical porous carbon for flexible all-solid-state supercapacitors [J].
Cao, Xiao-Man ;
Sun, Zhi-Jia ;
Zhao, Si-Yu ;
Wang, Bing ;
Han, Zheng-Bo .
MATERIALS CHEMISTRY FRONTIERS, 2018, 2 (09) :1692-1699
[9]   Reduced Graphene Oxide-Wrapped MoO3 Composites Prepared by Using Metal-Organic Frameworks as Precursor for All-Solid-State Flexible Supercapacitors [J].
Cao, Xiehong ;
Zheng, Bing ;
Shi, Wenhui ;
Yang, Jian ;
Fan, Zhanxi ;
Luo, Zhimin ;
Rui, Xianhong ;
Chen, Bo ;
Yan, Qingyu ;
Zhang, Hua .
ADVANCED MATERIALS, 2015, 27 (32) :4695-4701
[10]   Highly selective adsorption of Hg2+ by a polypyrrole-reduced graphene oxide composite [J].
Chandra, Vimlesh ;
Kim, Kwang S. .
CHEMICAL COMMUNICATIONS, 2011, 47 (13) :3942-3944