Chiral 3D architectures with helical channels constructed from polyoxometalate clusters and copper-amino acid complexes

被引:589
作者
An, HY [1 ]
Wang, EB [1 ]
Xiao, DR [1 ]
Li, YG [1 ]
Su, ZM [1 ]
Xu, L [1 ]
机构
[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Peoples R China
关键词
D O I
10.1002/anie.200503657
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A twist to the right, or to the left: Both enantiomers of a new chiral material were synthesized by a rational approach, using enantiopure proline ligands, copper cations, and Keggin polyoxometalate anions as building blocks. The compounds have open-framework structures containing helical channels. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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页码:904 / 908
页数:5
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