Lanthanide-based metal-organic frameworks as luminescent probes

被引:249
|
作者
Xu, Hang [1 ,2 ]
Cao, Chun-Shuai [1 ,2 ]
Kang, Xiao-Min [1 ,2 ]
Zhao, Bin [1 ,2 ]
机构
[1] Nankai Univ, Dept Chem, Key Lab Adv Energy Mat Chem, Tianjin 300071, Peoples R China
[2] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China
关键词
NEAR-INFRARED-LUMINESCENCE; SINGLE-MOLECULE MAGNETS; SELECTIVE FLUORESCENT-PROBE; STRUCTURED EU-MOF; COORDINATION POLYMERS; WHITE-LIGHT; HIGH-SENSITIVITY; AQUEOUS-SOLUTION; PICRIC ACID; NITROAROMATIC EXPLOSIVES;
D O I
10.1039/c6dt02213h
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Lanthanide-based metal-organic frameworks (Ln-MOFs), as notable materials, are constructed by Ln(3+) ions and organic ligands, or Ln(3+) ions functionalizing non-Ln-MOFs, and exhibit promising applications in various fields. Over the past decades, quite a lot of investigations of Ln-MOFs have been carried out, and many good results have been obtained. Among these results, Ln-MOFs as luminescent probes for unique detection are gradually becoming a hot topic due to their fast and effective luminescent response for the targeted substance. In this perspective article, we discuss the construction of luminescent Ln-MOFs, their applications in possible detection mechanisms, and summarize some examples of Ln-MOFs as luminescent probes for sensing cations, anions and small molecules.
引用
收藏
页码:18003 / 18017
页数:15
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