Patterns of solid-fluid phase equilibria: new possibilities?

被引：24

作者：

Garcia, DC ^{[1
]}

Luks, KD ^{[1
]}

机构：

[1] Univ Tulsa, Dept Chem Engn, Tulsa, OK 74104 USA

来源：

FLUID PHASE EQUILIBRIA | 1999年 / 161卷 / 01期

关键词：

solid-fluid equilibrium; van der Waals; binary mixtures;

D O I：

10.1016/S0378-3812(99)00163-6

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Thermodynamic phase space patterns of solid-liquid-vapor (slg) behavior in binary systems are reviewed. The van der Waals equation of state is used in combination with a common mathematical artifice for the solid-phase fugacity function to map out the sig loci for a model binary homologous series of solvent + solute mixtures as a function of the solute characterization. The computational results suggest the possible existence of a richer thermodynamic phase space topography than previously envisioned. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：91 / 106

页数：16

共 19 条

[1]

ARBUCKLE MM, 1989, FLUID PHASE EQUILIBR, V44, P295

[2]

DEITERS UK, 1986, ACS SYM SER, V300, P371

[3] CALCULATION OF EQUILIBRIA BETWEEN FLUID AND SOLID-PHASES IN BINARY-MIXTURES AT HIGH-PRESSURES FROM EQUATIONS OF STATE [J].