Synthesis of some platinum(II) diphosphine complexes of the type [PtX(2)(P-P)] (X(2)=CO3; X=CH3COO, CF3COO, NCO)

被引：9

作者：

Serindag, O

机构：

[1] Çukurova University, Faculty of Science and Arts, Chemistry Department, 01330 Balcali, Adana

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1997年 / 27卷 / 01期

关键词：

D O I：

10.1080/00945719708000183

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of aminobis(methylphosphine) complexes of platinum(II) with silver(I) salts in dichloromethane gives corresponding platinum(II) complexes of the type [PtX(2)(P-P)] where X(2) = CO3; X = CH3COO, CF3COO, NCO; P-P = (Cy(2)PCH(2))(2)NMe, dcpam; (Ph(2)PCH(2))(2)NMe, dppam). The complexes have been characterised by using spectroscopic techniques such as P-31-{H-1} and H-1 NMR, IR, and mass spectrometry.

引用

页码：69 / 76

页数：8

共 18 条

[1] PREPARATION AND PROPERTIES OF HYDROXO(METHYL)-1,2-BIS(DIPHENYLPHOSPHINO)ETHANEPLATINUM (II) - TRANS-INFLUENCE SERIES INCLUDING SIGMA-CARBON DONOR LIGANDS BASED ON PLATINUM-PHOSPHORUS COUPLING-CONSTANTS [J].