One-step synthesis of nanostructured mesoporous ZIF-8/silica composites

被引:74
作者
Hu, Xiaoyan [1 ]
Yan, Xinlong [1 ]
Zhou, Min [1 ]
Komarneni, Sridhar [2 ]
机构
[1] China Univ Min & Technol, Sch Chem Engn & Technol, Xuzhou 221116, Peoples R China
[2] Penn State Univ, Mat Res Inst, University Pk, PA 16802 USA
关键词
Mesoporous; ZIF-8; Composites; Surfactant; METAL-ORGANIC FRAMEWORKS; ZEOLITIC IMIDAZOLATE FRAMEWORK; POROUS COORDINATION POLYMERS; ROOM-TEMPERATURE SYNTHESIS; AQUEOUS-SOLUTION; FACILE SYNTHESIS; ZIF-8; NANOCRYSTALS; INSIGHT; STABILITY;
D O I
10.1016/j.micromeso.2015.06.046
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A series of mesoporous ZIF-8/silica composites were prepared by a one-step surfactant mediated method. The as-synthesized ZIF-8/silica composites were characterized by XRD, TEM, SEM, XPS, nitrogen adsorption/desorption and thermogravimetric (TG) analyses. Foam like disordered mesoporous structure and narrow mesopore size distribution were formed in the composites, resulting in a high mesopore volume as well as specific surface area which can be varied by adding different amounts of silica precursor. (C) 2015 Elsevier Inc. All rights reserved.
引用
收藏
页码:311 / 316
页数:6
相关论文
共 35 条
[1]   Investigation on Hydrogenation of Metal-Organic Frameworks HKUST-1, MIL-53, and ZIF-8 by Hydrogen Spillover [J].
Chen, Hao ;
Wang, Lifeng ;
Yang, Jun ;
Yang, Ralph T. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (15) :7565-7576
[2]   Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering [J].
Cravillon, Janosch ;
Nayuk, Roman ;
Springer, Sergej ;
Feldhoff, Armin ;
Huber, Klaus ;
Wiebcke, Michael .
CHEMISTRY OF MATERIALS, 2011, 23 (08) :2130-2141
[3]   Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework [J].
Cravillon, Janosch ;
Muenzer, Simon ;
Lohmeier, Sven-Jare ;
Feldhoff, Armin ;
Huber, Klaus ;
Wiebcke, Michael .
CHEMISTRY OF MATERIALS, 2009, 21 (08) :1410-1412
[4]   Highly Porous ZIF-8 Nanocrystals Prepared by a Surfactant Mediated Method in Aqueous Solution with Enhanced Adsorption Kinetics [J].
Fan, Xinxin ;
Wang, Wei ;
Li, Wei ;
Zhou, Junwen ;
Wang, Bo ;
Zheng, Jie ;
Li, Xingguo .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (17) :14994-14999
[5]   Hybrid porous solids:: past, present, future [J].
Ferey, Gerard .
CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) :191-214
[6]   Mesoporous silica-metal organic composite: synthesis, characterization, and ammonia adsorption [J].
Furtado, Amanda M. B. ;
Liu, Jian ;
Wang, Yu ;
Levan, M. Douglas .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (18) :6698-6706
[7]  
Horcajada P, 2010, NAT MATER, V9, P172, DOI [10.1038/NMAT2608, 10.1038/NMAT260B, 10.1038/nmat2608]
[8]   Ion Conductivity and Transport by Porous Coordination Polymers and Metal-Organic Frameworks [J].
Horike, Satoshi ;
Umeyama, Daiki ;
Kitagawa, Susumu .
ACCOUNTS OF CHEMICAL RESEARCH, 2013, 46 (11) :2376-2384
[9]   Integration of Porous Coordination Polymers and Gold Nanorods into Core-Shell Mesoscopic Composites toward Light-Induced Molecular Release [J].
Khaletskaya, Kira ;
Reboul, Julien ;
Meilikhov, Mikhail ;
Nakahama, Masashi ;
Diring, Stephane ;
Tsujimoto, Masahiko ;
Isoda, Seiji ;
Kim, Franklin ;
Kamei, Ken-ichiro ;
Fischer, Roland A. ;
Kitagawa, Susumu ;
Furukawa, Shuhei .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (30) :10998-11005
[10]   Formation of high crystalline ZIF-8 in an aqueous solution [J].
Kida, Koji ;
Okita, Muneyuki ;
Fujita, Kosuke ;
Tanaka, Shunsuke ;
Miyake, Yoshikazu .
CRYSTENGCOMM, 2013, 15 (09) :1794-1801