Graphene Oxide Nanosheets for Corrosion-Inhibiting Coating

被引:30
作者
Krishnamoorthy, Karthikeyan [1 ]
Ramadoss, Ananthakumar [1 ]
Kim, Sang-Jae [1 ,2 ]
机构
[1] Jeju Natl Univ, Dept Mech Syst Engn, Nanomat & Syst Lab, Cheju 690756, South Korea
[2] Jeju Natl Univ, Dept Mechatron Engn, Cheju 690756, South Korea
基金
新加坡国家研究基金会;
关键词
GO Thin Films; Chemical Synthesis; Electrochemical Properties; Impedance Spectroscopy; COPPER;
D O I
10.1166/sam.2013.1471
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this communication, we demonstrated the use of graphene oxide (GO) nanosheets for inhibition of Cu metal corrosion. GO nanosheets are synthesized according to the modified Hummers method and thin films of GO nanosheets are deposited onto copper substrates. Electrochemical methods, namely polarization analysis and electrochemical impedance spectroscopy techniques, are employed to study the corrosion inhibition of Cu using the GO coating. The protective efficiency of the GO-coated Cu substrates obtained from the Tafel analysis approaches 70% when compared to the bare copper substrate. Our results ensure the potential utility of GO towards their applications in the development of corrosion-resistant coatings.
引用
收藏
页码:406 / 410
页数:5
相关论文
共 25 条
[1]   Electrochemical corrosion and materials properties of reactively sputtered TiN/TiAlN multilayer coatings [J].
Ananthakumar, R. ;
Subramanian, B. ;
Kobayashi, Akira ;
Jayachandran, M. .
CERAMICS INTERNATIONAL, 2012, 38 (01) :477-485
[2]   Corrosion protection of ENIG surface finishing using electrochemical methods [J].
Bui, Q. V. ;
Nam, N. D. ;
Choi, D. H. ;
Lee, J. B. ;
Lee, C. Y. ;
Kar, A. ;
Kim, J. G. ;
Jung, S. B. .
MATERIALS RESEARCH BULLETIN, 2010, 45 (03) :305-308
[3]   Impermeable atomic membranes from graphene sheets [J].
Bunch, J. Scott ;
Verbridge, Scott S. ;
Alden, Jonathan S. ;
van der Zande, Arend M. ;
Parpia, Jeevak M. ;
Craighead, Harold G. ;
McEuen, Paul L. .
NANO LETTERS, 2008, 8 (08) :2458-2462
[4]   Dispersion Stability of Metal (Oxide)-Graphene Nanofluids with Electrical and Thermal Properties [J].
Chen, Ming-Liang ;
Meng, Ze-Da ;
Zhu, Lei ;
Choi, Jong-Geun ;
Park, Chong-Yeon ;
Lee, Shi-Choon ;
Hong, Dae-Seung ;
Lee, Jeong-Geol ;
Jang, Won-Kweon ;
Oh, Won-Chun .
SCIENCE OF ADVANCED MATERIALS, 2011, 3 (06) :887-892
[5]   Oxidation Resistance of Graphene-Coated Cu and Cu/Ni Alloy [J].
Chen, Shanshan ;
Brown, Lola ;
Levendorf, Mark ;
Cai, Weiwei ;
Ju, Sang-Yong ;
Edgeworth, Jonathan ;
Li, Xuesong ;
Magnuson, Carl W. ;
Velamakanni, Aruna ;
Piner, Richard D. ;
Kang, Junyong ;
Park, Jiwoong ;
Ruoff, Rodney S. .
ACS NANO, 2011, 5 (02) :1321-1327
[6]   The chemistry of graphene oxide [J].
Dreyer, Daniel R. ;
Park, Sungjin ;
Bielawski, Christopher W. ;
Ruoff, Rodney S. .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :228-240
[7]   Inhibition effect of 4-amino-antipyrine on the corrosion of copper in 3 wt.% NaCl solution [J].
Hong, Song ;
Chen, Wen ;
Luo, Hong Qun ;
Li, Nian Bing .
CORROSION SCIENCE, 2012, 57 :270-278
[8]  
Krishnamoorthy K., 2012, SCI ADV MATER, V4, P1
[9]   Antibacterial Efficiency of Graphene Nanosheets against Pathogenic Bacteria via Lipid Peroxidation [J].
Krishnamoorthy, Karthikeyan ;
Veerapandian, Murugan ;
Zhang, Ling-He ;
Yun, Kyusik ;
Kim, Sang Jae .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (32) :17280-17287
[10]   Investigation of Raman and photoluminescence studies of reduced graphene oxide sheets [J].
Krishnamoorthy, Karthikeyan ;
Veerapandian, Murugan ;
Mohan, Rajneesh ;
Kim, Sang-Jae .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2012, 106 (03) :501-506