A feasible approach to the synthesis of nickel phosphide for hydrodesulfurization

被引：84

作者：

Guan, Qingxin ^{[1
]}

Cheng, Xun ^{[1
]}

Li, Rongguan ^{[1
]}

Li, Wei ^{[1
]}

机构：

[1] Nankai Univ, Key Lab Adv Energy Mat Chem, Minist Educ, Coll Chem, Tianjin 300071, Peoples R China

来源：

JOURNAL OF CATALYSIS | 2013年 / 299卷

关键词：

Desulfurization; Hydrogen; Metal phosphide; Nickel; Phosphate; TRANSITION-METAL PHOSPHIDES; CATALYSTS; PHOSPHORUS; PRECURSORS; PHASE; DIBENZOTHIOPHENE; REDUCTION; NI2P/SIO2; ROUTE; NI;

D O I：

10.1016/j.jcat.2012.11.008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this paper, we propose a simple and feasible method for synthesizing bulk and supported nickel phosphides from oxide precursors. The new approach uses a low hydrogen flow speed and is not affected by the heating rate. The results indicate that Ni2P can be synthesized at 600 degrees C from its oxide precursors with a mole ratio of Ni/P = 2/1. The hydrodesulfurization activity results indicate that the direct-reduction method shows excellent performance in the synthesis of supported catalysts. (c) 2012 Elsevier Inc. All rights reserved.

引用

页码：1 / 9

页数：9

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