A simple and straightforward approach toward selective C=C bond reduction by hydrazine

被引：22

作者：

Chen, Hao ^{[1
]}

Wang, Jianmin ^{[1
]}

Hong, Xuechuan ^{[1
]}

Zhou, Hai-Bing ^{[1
]}

Dong, Chune ^{[1
]}

机构：

[1] Wuhan Univ, Sch Pharmaceut Sci, Key Lab Combinatorial Biosynth & Drug Discovery, Minist Educ,State Key Lab Virol, Wuhan 430071, Peoples R China

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 2012年 / 90卷 / 09期

基金：

高等学校博士学科点专项科研基金;

关键词：

hydrazine; reduction; C = C double bond; MULTIPLE BONDS; DIIMIDE; HYDROGENATION; ALCOHOLS; OLEFINS;

D O I：

10.1139/V2012-057

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple and straightforward method for reducing the C = C double bond with hydrazine is described. A number of representative C = C bonds in various steric and electronic environments were examined. Substituted alkenes can be selectively reduced in EtOH in the presence of hydrazine to give the corresponding products in up to 100% yields.

引用

页码：758 / 761

页数：4

共 23 条

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[2]

[Anonymous], 1992, APPL ORGANOMET CHEM

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