Metallic Impurities in Graphenes Prepared from Graphite Can Dramatically Influence Their Properties

被引:162
作者
Ambrosi, Adriano [1 ]
Chee, Sze Yin [1 ]
Khezri, Bahareh [1 ]
Webster, Richard D. [1 ]
Sofer, Zdenek [2 ]
Pumera, Martin [1 ]
机构
[1] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Phys & Math Sci, Singapore 637371, Singapore
[2] Inst Chem Technol, Dept Inorgan Chem, CR-16628 Prague 6, Czech Republic
关键词
electrochemistry; graphene; graphite; impurities; NANOTUBE-MODIFIED ELECTRODES; WALL CARBON NANOTUBES; LARGE-AREA; OXIDE; ELECTROCHEMISTRY; NANOPARTICLES; BIOAVAILABILITY; CYTOTOXICITY; OXIDATION; HYDROGEN;
D O I
10.1002/anie.201106917
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
All at C? Graphenes prepared by the top-down exfoliation of graphite are shown to contain metallic impurities (see scheme, metal impurities shown as black dots). These impurities may dominate their properties and can have a negative influence on their potential applications. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:500 / 503
页数:4
相关论文
共 49 条
[1]   Honeycomb Carbon: A Review of Graphene [J].
Allen, Matthew J. ;
Tung, Vincent C. ;
Kaner, Richard B. .
CHEMICAL REVIEWS, 2010, 110 (01) :132-145
[2]   Electrochemistry at Chemically Modified Graphenes [J].
Ambrosi, Adriano ;
Bonanni, Alessandra ;
Sofer, Zdenek ;
Cross, Jeffrey S. ;
Pumera, Martin .
CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (38) :10763-10770
[3]   Regulatory Peptides Are Susceptible to Oxidation by Metallic Impurities within Carbon Nanotubes [J].
Ambrosi, Adriano ;
Pumera, Martin .
CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (06) :1786-1792
[4]  
[Anonymous], 2005, ANGEW CHEM
[5]  
[Anonymous], 2009, ANGEW CHEM
[6]   Microwave-promoted Heck coupling using ultralow metal catalyst concentrations [J].
Arvela, RK ;
Leadbeater, NE .
JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (05) :1786-1790
[7]  
Banks C.E., 2006, Angew. Chem, V118, P2595
[8]   Carbon nanotubes contain metal impurities which are responsible for the "electrocatalysis" seen at some nanotube-modified electrodes [J].
Banks, CE ;
Crossley, A ;
Salter, C ;
Wilkins, SJ ;
Compton, RG .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (16) :2533-2537
[9]   Copper oxide nanoparticle impurities are responsible for the electroanalytical detection of glucose seen using multiwalled carbon nanotubes [J].
Batchelor-McAuley, Christopher ;
Wildgoose, Gregory G. ;
Compton, Richard G. ;
Shao, Lidong ;
Green, Malcolm L. H. .
SENSORS AND ACTUATORS B-CHEMICAL, 2008, 132 (01) :356-360
[10]   On the Role of Metal Contaminants in Catalyses with FeCl3 [J].
Buchwald, Stephen L. ;
Bolm, Carsten .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (31) :5586-5587