Multifunctional applications of a dysprosium-based metal-organic chain with single-ion magnet behaviour

被引：26
作者：
Fernandez, Belen [1 ]
Oyarzabal, Itziar [2 ]
Fischer-Fodor, Eva [3 ,4 ]
Macavei, Sergiu [5 ]
Sanchez, Ignacio [1 ]
Seco, Jose M. [2 ]
Gomez-Ruiz, Santiago [6 ]
Rodriguez-Dieguez, Antonio [1 ]
机构：
[1] Univ Granada, Dept Inorgan Chem, E-18071 Granada, Spain
[2] Univ Basque Country UPV EHU, Dept Appl Chem, San Sebastian 20018, Spain
[3] Inst Oncol I Chiricuta, Res Dept, Cluj Napoca 400015, Romania
[4] Univ Med & Pharm Iuliu Hatieganu Cluj Napoca, Medfuture Res Ctr, Cluj Napoca 400012, Romania
[5] Natl Inst R&D Isotop & Mol Technol, Cluj Napoca 400293, Romania
[6] Dept Biol & Geol Fis & Quim Inorgan, Calle Tulipon S-N, Madrid 28933, Spain
来源：
CRYSTENGCOMM | 2016年 / 18卷 / 45期
关键词：
ZN-DY; FLUORESCENCE; RELAXATION; FRAMEWORKS; COMPLEXES;
D O I：
10.1039/c6ce01810f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel metal-organic chain constructed of dysprosium and sodium ions based on 5-aminopyridine-2-carboxylic acid has been synthesized and characterized. The formation of this 1D-MOF is achieved using a soft solvothermal route with dimethylformamide as solvent. This material displays intense photoluminescence properties in the solid state at room temperature and exhibits SIM behavior with frequency dependence of the out-of-phase susceptibility at zero dc field. More interesting, we report here the magnetic field dependent cytotoxicity and multidrug-resistant properties of this 1D-MOF. This multidisciplinary preliminary study of the applications of this metal complex opens up the possibility of further investigations in the fields of metal-based drugs, luminescence and magnetism.
引用
收藏
页码：8718 / 8721
页数：4
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