Zero-field splitting in pentacoordinate Co(II) complexes

被引：35

作者：

Rajnak, C. ^{[1
,2
]}

Titis, J. ^{[1
]}

Salitros, I. ^{[3
,4
]}

Boca, R. ^{[1
]}

Fuhr, O. ^{[4
]}

Ruben, M. ^{[2
,4
]}

机构：

[1] Univ SS Cyril & Methodius, FPV, Dept Chem, SK-91701 Trnava, Slovakia

[2] Univ Strasbourg, CNRS, UMR 7504, IPCMS, F-67034 Strasbourg, France

[3] Slovak Univ Technol Bratislava, FCHPT, Inst Inorgan Chem, SK-81237 Bratislava, Slovakia

[4] Karlsruhe Inst Technol, Inst Nanotechnol, D-76344 Eggenstein Leopoldshafen, Germany

来源：

POLYHEDRON | 2013年 / 65卷

关键词：

Cobalt(II) complex; Crystal structure; Zero-field splitting; Magnetostructural D-correlation; DINUCLEAR COPPER(II) COMPLEXES; HETEROLEPTIC NICKEL(II) COMPLEXES; MAGNETO STRUCTURAL CORRELATIONS; TEMPERATURE SPIN TRANSITION; CRYSTAL-STRUCTURE; COBALT(II) COMPLEXES; CARBOXYLATO BRIDGES; MOLECULAR-STRUCTURE; LIGAND; DIMERS;

D O I：

10.1016/j.poly.2013.08.029

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pentacoordinate Co(II) complexes possessing the {CoN3X2) chromophore (X = Cl, O) have been synthesized and structurally characterized. The magnetic data confirm high magnetic anisotropy expressed through the axial zero-field splitting parameter D/hc = 50-70 cm(-1). These values lie between those found in tetracoordinate and hexacoordinate Co(II) complexes. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：122 / 128

页数：7

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