Advancements in oxazolidinone synthesis utilizing carbon dioxide as a C1 source

被引：95

作者：

Pulla, Sharon ^{[1
]}

Felton, Charlette M. ^{[1
]}

Ramidi, Punnamchandar ^{[1
]}

Gartia, Yashraj ^{[1
]}

Ali, Nawab ^{[2
]}

Nasini, Udaya B. ^{[1
]}

Ghosh, Anindya ^{[1
]}

机构：

[1] Univ Arkansas, Dept Chem, Little Rock, AR 72204 USA

[2] Univ Arkansas, Dept Appl Sci, Little Rock, AR 72204 USA

来源：

JOURNAL OF CO2 UTILIZATION | 2013年 / 2卷

基金：

美国国家科学基金会;

关键词：

Oxazolidinones; Carbon dioxide; Aziridine; Propargylamine; Amino alcohol; SELECTIVE SYNTHESIS; CYCLIC UREAS; RECYCLABLE CATALYST; HIGHLY EFFICIENT; AZIRIDINES; CO2; 5-ARYL-2-OXAZOLIDINONES; CYCLOADDITION; 2-OXAZOLIDINONES; CONVERSION;

D O I：

10.1016/j.jcou.2013.07.005

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon dioxide, a natural molecule, has been utilized in the synthesis of chemicals for several decades. Its innocuous chemical properties make it a favorable substance to incorporate in such synthetic processes. Recently, research is being conducted to include carbon dioxide in the production of a specific class of cyclic urethane molecules known as oxazolidinones. Oxazolidinones are important in synthetic and medicinal applications, which necessitate a greener method to produce them. In this review, various synthetic methods including catalytic processes that incorporate carbon dioxide to yield oxazolidinones have been discussed and the results of the research are presented. Emphasis is placed primarily on reactions of carbon dioxide with a variety of aziridines, propargylamines and 2-amino alcohols for the synthesis of oxazolidinones. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：49 / 57

页数：9

共 50 条

[1] The reaction of 1,2-amino alcohols with carbon dioxide in the presence of 2-pyrrolidone electrogenerated base. New synthesis of chiral oxazolidin-2-ones [J].