Critical review of the molecular design progress in non-fullerene electron acceptors towards commercially viable organic solar cells

被引：858
作者：
Wadsworth, Andrew [1 ,2 ]
Moser, Maximilian [1 ,2 ]
Marks, Adam [1 ,2 ]
Little, Mark S. [1 ,2 ]
Gasparini, Nicola [3 ,4 ]
Brabec, Christoph J. [3 ,5 ]
Baran, Derya [4 ]
McCulloch, Iain [1 ,2 ,4 ]
机构：
[1] Imperial Coll London, Dept Chem, London SW7 2AZ, England
[2] Imperial Coll London, Ctr Plast Elect, London SW7 2AZ, England
[3] Friedrich Alexander Univ Erlangen Nuremberg, I MEET, Martensstr 7, D-91058 Erlangen, Germany
[4] King Abdullah Univ Sci & Technol KAUST, Phys Sci & Engn Div, KAUST Solar Ctr KSC, Ksc Thuwal 239556900, Saudi Arabia
[5] Bavarian Ctr Appl Energy Res ZAE Bayern, Haberstr 2a, D-91058 Erlangen, Germany
来源：
CHEMICAL SOCIETY REVIEWS | 2019年 / 48卷 / 06期
基金：
英国工程与自然科学研究理事会;
关键词：
POWER CONVERSION EFFICIENCY; VERSATILE BUILDING-BLOCKS; HIGH-PERFORMANCE; PHOTOVOLTAIC PERFORMANCE; CONJUGATED POLYMERS; EXCITON DIFFUSION; HIGHLY EFFICIENT; CROSS-LINKING; 3D STRUCTURE; MORPHOLOGY;
D O I：
10.1039/c7cs00892a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Fullerenes have formed an integral part of high performance organic solar cells over the last 20 years, however their inherent limitations in terms of synthetic flexibility, cost and stability have acted as a motivation to develop replacements; the so-called non-fullerene electron acceptors. A rapid evolution of such materials has taken place over the last few years, yielding a number of promising candidates that can exceed the device performance of fullerenes and provide opportunities to improve upon the stability and processability of organic solar cells. In this review we explore the structure-property relationships of a library of non-fullerene acceptors, highlighting the important chemical modifications that have led to progress in the field and provide an outlook for future innovations in electron acceptors for use in organic photovoltaics.
引用
收藏
页码：1596 / 1625
页数：30
相关论文
共 140 条
  • [1] Performance Enhancement of the P3HT/PCBM Solar Cells through NIR Sensitization Using a Small-Bandgap Polymer
    Ameri, Tayebeh
    Min, Jie
    Li, Ning
    Machui, Florian
    Baran, Derya
    Forster, Michael
    Schottler, Kristina J.
    Dolfen, Daniel
    Scherf, Ullrich
    Brabec, Christoph J.
    [J]. ADVANCED ENERGY MATERIALS, 2012, 2 (10) : 1198 - 1202
  • [2] Reduced voltage losses yield 10% efficient fullerene free organic solar cells with >1 V open circuit voltages
    Baran, D.
    Kirchartz, T.
    Wheeler, S.
    Dimitrov, S.
    Abdelsamie, M.
    Gorman, J.
    Ashraf, R. S.
    Holliday, S.
    Wadsworth, A.
    Gasparini, N.
    Kaienburg, P.
    Yan, H.
    Amassian, A.
    Brabec, C. J.
    Durrant, J. R.
    McCulloch, I.
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (12) : 3783 - 3793
  • [3] Baran D, 2017, NAT MATER, V16, P363, DOI [10.1038/NMAT4797, 10.1038/nmat4797]
  • [4] White-light bias external quantum efficiency measurements of standard and inverted P3HT: PCBM photovoltaic cells
    Brenner, Thomas J. K.
    Vaynzof, Yana
    Li, Zhe
    Kabra, Dinesh
    Friend, Richard H.
    McNeill, Christopher R.
    [J]. JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2012, 45 (41)
  • [5] Matrix Organization and Merit Factor Evaluation as a Method to Address the Challenge of Finding a Polymer Material for Roll Coated Polymer Solar Cells
    Bundgaard, Eva
    Livi, Francesco
    Hagemann, Ole
    Carle, Jon E.
    Helgesen, Martin
    Heckler, Ilona M.
    Zawacka, Natalia K.
    Angmo, Dechan
    Larsen-Olsen, Thue T.
    Benatto, Gisele A. dos Reis
    Roth, Berenger
    Madsen, Morten V.
    Andersson, Mats R.
    Jorgensen, Mikkel
    Sondergaard, Roar R.
    Krebs, Frederik C.
    [J]. ADVANCED ENERGY MATERIALS, 2015, 5 (10)
  • [6] Polymer solar cells spray coated with non-halogenated solvents
    Cai, Chaosheng
    Zhang, Yangdong
    Song, Rongying
    Peng, Zuosheng
    Xia, Lianpeng
    Wu, Mingxiao
    Xiong, Kang
    Wang, Biao
    Lin, Yuanbao
    Xu, Xiaofeng
    Liang, Quanbing
    Wu, Hongbin
    Wang, Ergang
    Hou, Lintao
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2017, 161 : 52 - 61
  • [7] Morphology evolution via self-organization and lateral and vertical diffusion in polymer: fullerene solar cell blends
    Campoy-Quiles, Mariano
    Ferenczi, Toby
    Agostinelli, Tiziano
    Etchegoin, Pablo G.
    Kim, Youngkyoo
    Anthopoulos, Thomas D.
    Stavrinou, Paul N.
    Bradley, Donal D. C.
    Nelson, Jenny
    [J]. NATURE MATERIALS, 2008, 7 (02) : 158 - 164
  • [8] Comparative studies of photochemical cross-linking methods for stabilizing the bulk hetero-junction morphology in polymer solar cells
    Carle, Jon Eggert
    Andreasen, Birgitta
    Tromholt, Thomas
    Madsen, Morten V.
    Norrman, Kion
    Jorgensen, Mikkel
    Krebs, Frederik C.
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (46) : 24417 - 24423
  • [9] Effect of Trace Solvent on the Morphology of P3HT:PCBM Bulk Heterojunction Solar Cells
    Chang, Lilian
    Lademann, Hans W. A.
    Bonekamp, Joerg-Bernd
    Meerholz, Klaus
    Moule, Adam J.
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (10) : 1779 - 1787
  • [10] Recent progress in non-fullerene small molecule acceptors in organic solar cells (OSCs)
    Chen, Wangqiao
    Zhang, Qichun
    [J]. JOURNAL OF MATERIALS CHEMISTRY C, 2017, 5 (06) : 1275 - 1302
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