Zn3(BTC)2 as a Highly Efficient Reusable Catalyst for the Synthesis of 2-Aryl-1H-Benzimidazole

被引:34
作者
Sajjadifar, Sami [1 ]
Arzehgar, Zeinab [1 ]
Ghayuri, Azadeh [1 ]
机构
[1] Payame Noor Univ, Dept Chem, Ilam, Iran
关键词
Zn-3(BTC)(2); Benzimidazoles; o-Phenylendiamine; Aldehydes; Metal-organic frameworks; METAL-ORGANIC FRAMEWORKS; BENZIMIDAZOLE DERIVATIVES; BIOLOGICAL EVALUATION; 2-ARYLBENZIMIDAZOLES; SOLIDS; DESIGN; LIGAND; AIR;
D O I
10.1002/jccs.201700266
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Zn-3(BTC)(2) metal-organic frameworks as recyclable and heterogeneous catalysts were effectively used to catalyze the synthesis of benzimidazole derivatives from o-phenylendiamine and aldehydes in ethanol. This method provides 2-aryl-1H-benzimidazoles in good to excellent yields with little catalyst loading. The catalyst was characterized using different techniques such as X-ray diffraction (XRD), energy dispersive X-ray (EDX) analysis, scanning electron microscopy (SEM), and Fourier transform infrared (FT-IR) spectroscopy.
引用
收藏
页码:205 / 211
页数:7
相关论文
共 48 条
  • [1] [Anonymous], 2003, TETRAHEDRON LETT, DOI DOI 10.1016/S0040-4039(03)01387-X
  • [2] Synthesis of benzimidazoles and benzoxazoles using TiCl3OTf in ethanol at room temperature
    Azizian, Javad
    Torabi, Parviz
    Noei, Jalil
    [J]. TETRAHEDRON LETTERS, 2016, 57 (02) : 185 - 188
  • [3] Mild and highly efficient method for the synthesis of 2-arylbenzimidazoles and 2-arylbenzothiazoles
    Bahrami, Kiumars
    Khodaei, M. Mehdi
    Naali, Fardin
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2008, 73 (17) : 6835 - 6837
  • [4] Selective and eco-friendly procedures for the synthesis of benzimidazole derivatives. The role of the Er(OTf)3 catalyst in the reaction selectivity
    Cano, Natividad Herrera
    Uranga, Jorge G.
    Nardi, Monica
    Procopio, Antonio
    Wunderlin, Daniel A.
    Santiago, Ana N.
    [J]. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2016, 12 : 2410 - 2419
  • [5] Metal-organic frameworks: versatile heterogeneous catalysts for efficient catalytic organic transformations
    Chughtai, Adeel H.
    Ahmad, Nazir
    Younus, Hussein A.
    Laypkov, A.
    Verpoort, Francis
    [J]. CHEMICAL SOCIETY REVIEWS, 2015, 44 (19) : 6804 - 6849
  • [6] Deria P, 2014, CHEM SOC REV, V43, P5896, DOI [10.1039/C4CS00067F, 10.1039/c4cs00067f]
  • [7] Metal-organic frameworks catalyzed C-C and C-heteroatom coupling reactions
    Dhakshinamoorthy, Amarajothi
    Asiri, Abdullah M.
    Garcia, Hermenegildo
    [J]. CHEMICAL SOCIETY REVIEWS, 2015, 44 (07) : 1922 - 1947
  • [8] Delineating similarities and dissimilarities in the use of metal organic frameworks and zeolites as heterogeneous catalysts for organic reactions
    Dhakshinamoorthy, Amarajothi
    Alvaro, Mercedes
    Corma, Avelino
    Garcia, Hermenegildo
    [J]. DALTON TRANSACTIONS, 2011, 40 (24) : 6344 - 6360
  • [9] Aerobic Oxidation of Benzylic Alcohols Catalyzed by Metal-Organic Frameworks Assisted by TEMPO
    Dhakshinamoorthy, Amarajothi
    Alvaro, Mercedes
    Garcia, Hermenegildo
    [J]. ACS CATALYSIS, 2011, 1 (01): : 48 - 53
  • [10] Zn2+-K10-clay (clayzic) as an efficient water-tolerant, solid acid catalyst for the synthesis of benzimidazoles and quinoxalines at room temperature
    Dhakshinamoorthy, Amarajothi
    Kanagaraj, Kuppusamy
    Pitchumani, Kasi
    [J]. TETRAHEDRON LETTERS, 2011, 52 (01) : 69 - 73