Comparison of additive and reactive phosphorus-based flame retardants in epoxy resins

被引：36

作者：

Szolnoki, Beata ^{[1
]}

Toldy, Andrea ^{[2
]}

Konrad, Peter ^{[2
]}

Szebenyi, Gabor ^{[2
]}

Marosi, Gyoergy ^{[1
]}

机构：

[1] Budapest Univ Technol & Econ, Dept Organ Chem & Technol, H-1111 Budapest, Hungary

[2] Budapest Univ Technol & Econ, Dept Polymer Engn, H-1111 Budapest, Hungary

来源：

PERIODICA POLYTECHNICA-CHEMICAL ENGINEERING | 2013年 / 57卷 / 1-2期

关键词：

additive and reactive flame retardancy; epoxy resin; DOPO; ammonium polyphosphate; cone calorimeter; AMMONIUM POLYPHOSPHATE; PART I; COMPOSITES; POLYPROPYLENE; PERFORMANCE; OXIDATION;

D O I：

10.3311/PPch.2175

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The aim of this work was to investigate the effect of phosphorus-based additive and reactive flame retardants (FR) on the flammability and mechanical properties of a pentaerythritol-based model epoxy resin system cured with a cycloaliphatic diamine hardener. Commercially available ammonium polyphosphate (APP) was used as additive and 9,10-dihydro-9-oxa-10-phosphaphenantrene-10-oxide (DOPO) as reactive flame retardant. The behaviour of these systems was also compared to a recently synthesized phosphorus-containing amine (TEDAP), which can be used both as flame retardant and crosslinking agent.

引用

页码：85 / 91

页数：7

共 24 条

[1]

BARKANYI A, 2012, PERIOD POLYTECH, V56, P55, DOI DOI 10.3311/PP.CH.2012-2.02

[2] Self-extinguishing polypropylene with a mass fraction of 9% intumescent additive - A new physical way for enhancing the fire retardant efficiency [J].

Bocz, Katalin ;

Barany, Tumas ;

Toldy, Andrea ;

Bodzay, Brigitta ;

Csontos, Istvan ;

Madi, Kinga ;

Marosi, Gyoergy .

POLYMER DEGRADATION AND STABILITY, 2013, 98 (01) :79-86

[3] Influence of the oxidation state of phosphorus on the decomposition and fire behaviour of flame-retarded epoxy resin composites [J].

Braun, Ulrike ;

Balabanovich, Aliaksandr I. ;

Schartel, Bernhard ;

Knoll, Uta ;

Artner, Johannes ;

Ciesielski, Michael ;

Doering, Manfred ;

Perez, Raul ;

Sandler, Jan K. W. ;

Altstaedt, Volker ;

Hoffmann, Thorsten ;

Pospiech, Doris .

POLYMER, 2006, 47 (26) :8495-8508

[4] Flame retardant aircraft epoxy resins containing phosphorus [J].

Hergenrother, PM ;

Thompson, CM ;

Smith, JG ;

Connell, JW ;

Hinkley, JA ;

Lyon, RE ;

Moulton, R .

POLYMER, 2005, 46 (14) :5012-5024

[5] Catalytic wet oxidation of real process wastewaters [J].

Hosseini, Arezoo M. ;

Tungler, Antal ;

Horvath, E. Zsolt ;

Shay, Zoltan ;

Szeles, Eva .

PERIODICA POLYTECHNICA-CHEMICAL ENGINEERING, 2011, 55 (02) :49-57

[6] Mechanical performance of heat/fire damaged novel flame retardant glass-reinforced epoxy composites [J].

Kandola, BK ;

Horrocks, AR ;

Myler, P ;

Blair, D .

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2003, 34 (09) :863-873

[7] Synergistic effect between a novel hyperbranched charring agent and ammonium polyphosphate on the flame retardant and anti-dripping properties of polylactide [J].

Ke, Chen-Hao ;

Li, Juan ;

Fang, Ke-Yi ;

Zhu, Qi-Liang ;

Zhu, Jin ;

Yan, Qing ;

Wang, Yu-Zhong .

POLYMER DEGRADATION AND STABILITY, 2010, 95 (05) :763-770

[8] Effect of intumescent ammonium polyphosphate (APP) and melamine cyanurate (MC) on the properties of epoxy/glass fiber composites [J].

Lim, W. K. Patrick ;

Mariatti, M. ;

Chow, W. S. ;

Mar, K. T. .

COMPOSITES PART B-ENGINEERING, 2012, 43 (02) :124-128

[9] Novel phosphorus-containing epoxy resins Part I. Synthesis and properties [J].

Lin, CH ;

Wang, CS .

POLYMER, 2001, 42 (05) :1869-1878

[10] The influence of KH-550 on properties of ammonium polyphosphate and polypropylene flame retardant composites [J].

Lin, Hongjiao ;

Yan, Hong ;

Liu, Bo ;

Wei, Liqiao ;

Xu, Bingshe .

POLYMER DEGRADATION AND STABILITY, 2011, 96 (07) :1382-1388

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