Batchwise and Continuous Nanofiltration of POSS-Tagged Grubbs-Hoveyda-Type Olefin Metathesis Catalysts

被引：57
|
作者：
Kajetanowicz, Anna [1 ]
Czaban, Justyna [1 ]
Krishnan, G. Rajesh [1 ]
Malinska, Maura [2 ]
Wozniak, Krzysztof [2 ]
Siddique, Humera [3 ]
Peeva, Ludmila G. [3 ]
Livingston, Andrew G. [3 ]
Grela, Karol [1 ]
机构：
[1] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland
[2] Univ Warsaw, Dept Chem, PL-02089 Warsaw, Poland
[3] Univ London Imperial Coll Sci Technol & Med, Dept Chem Engn, London SW7 2AZ, England
来源：
CHEMSUSCHEM | 2013年 / 6卷 / 01期
基金：
英国工程与自然科学研究理事会;
关键词：
homogeneous catalysis; membranes; metathesis; microporous materials; ruthenium; RUTHENIUM BY-PRODUCTS; EFFICIENT REMOVAL; CONVENIENT METHOD; SEPARATION; SILSESQUIOXANE; MEMBRANE; NANOPARTICLES; COMPLEXES; OXIDATION; RECOVERY;
D O I：
10.1002/cssc.201200466
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New molecular-weight-enlarged metathesis catalysts, which bear polyhedral oligomeric silsesquioxane (POSS) tags, were synthesized and characterized. The catalysts can be recovered from the reaction mixture by using nanofiltration techniques and can be reused. It was found that the membranes Starmem 228 and PuraMem 280 successfully separate the catalyst from the post-reaction mixtures to below 3 ppm. The application of these POSS-tagged catalysts in a continuous metathesis reaction was also investigated.
引用
收藏
页码：182 / 192
页数：11
相关论文
共 42 条
  • [21] Grubbs-Hoveyda type catalysts bearing a dicationic N-heterocyclic carbene for biphasic olefin metathesis reactions in ionic liquids
    Koy, Maximilian
    Altmann, Hagen J.
    Autenrieth, Benjamin
    Frey, Wolfgang
    Buchmeiser, Michael R.
    BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2015, 11 : 1632 - 1638
  • [22] Synthesis and Characterization of Sterically Enlarged Hoveyda-Type Olefin Metathesis Catalysts
    Shahane, Saurabh
    Toupet, Loic
    Fischmeister, Cedric
    Bruneau, Christian
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, (01) : 54 - 60
  • [23] Metathesis of cardanol over ammonium tagged Hoveyda-Grubbs type catalyst supported on SBA-15
    Balcar, Hynek
    Zilkova, Nadezda
    Kubu, Martin
    Polasek, Miroslav
    Zednik, Jiri
    CATALYSIS TODAY, 2018, 304 : 127 - 134
  • [24] Acyclic diene metathesis polymerization of divinylarenes and divinylferrocenes with Grubbs-type olefin metathesis catalysts
    Weychardt, Holger
    Plenio, Herbert
    ORGANOMETALLICS, 2008, 27 (07) : 1479 - 1485
  • [25] Separation of different metathesis Grubbs-type catalysts using organic solvent nanofiltration
    van der Gryp, Percy
    Barnard, Anro
    Cronje, Jean-Pierre
    de Vlieger, Dennis
    Marx, Sanette
    Vosloo, Hermanus C. M.
    JOURNAL OF MEMBRANE SCIENCE, 2010, 353 (1-2) : 70 - 77
  • [26] Significant substituent effect of ligand '2-isopropoxystyrene' on the activity and stability of Hoveyda-Grubbs catalysts for olefin metathesis.
    Zhan, ZYJ
    Liu, JC
    Zhang, GY
    Cai, YX
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U337 - U337
  • [27] DFT Mechanistic Study on Diene Metathesis Catalyzed by Ru-Based Grubbs-Hoveyda-Type Carbenes: The Key Role of Tr-Electron Density De localization in the Hoveyda Ligand
    Solans-Monfort, Xavier
    Pleixats, Roser
    Sodupe, Mariona
    CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (24) : 7331 - 7343
  • [28] Activated Hoveyda-Grubbs Olefin Metathesis Catalysts Derived from a Large Scale Produced Pharmaceutical Intermediate - Sildenafil Aldehyde
    Monsigny, Louis
    Piatkowski, Jakub
    Trzybinski, Damian
    Wozniak, Krzysztof
    Nienaltowski, Tomasz
    Kajetanowicz, Anna
    Grela, Karol
    ADVANCED SYNTHESIS & CATALYSIS, 2021, 363 (19) : 4590 - 4604
  • [29] Structural analogues of Hoveyda-Grubbs catalysts bearing the 1-benzofuran moiety or isopropoxy-1-benzofuran derivatives as olefin metathesis catalysts
    Trzaskowski, B.
    Ostrowska, K.
    RSC ADVANCES, 2016, 6 (26): : 21423 - 21429
  • [30] Advanced fine-tuning of Grubbs/Hoveyda olefin metathesis catalysts: a further step toward an optimum balance between antinomic properties
    Bieniek, Michal
    Bujok, Robert
    Cabaj, Maciej
    Lugan, Noel
    Lavigne, Guy
    Arlt, Dieter
    Grela, Karol
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (42) : 13652 - 13653
12345