Highly efficient reduction of graphene oxide using ammonia borane

被引：90

作者：

Viet Hung Pham ^{[1
]}

Hur, Seung Hyun ^{[1
]}

Kim, Eui Jung ^{[1
]}

Kim, Bum Sung ^{[2
]}

Chung, Jin Suk ^{[1
]}

机构：

[1] Univ Ulsan, Sch Chem Engn & Bioengn, Ulsan 680749, South Korea

[2] KCC Cent Res Inst, Yonginsi 446716, Gyunggido, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 59期

基金：

新加坡国家研究基金会;

关键词：

CHEMICALLY CONVERTED GRAPHENE; ORGANIC-SOLVENTS; SUPERCAPACITORS; FILMS; GENERATION; SUSPENSION; HYDROGEN; STORAGE; ROUTE;

D O I：

10.1039/c3cc43503b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We introduce ammonia borane, a versatile reducing agent for graphene oxide (GO) reduction in both aqueous and organic solvents; it is nontoxic and more effective than hydrazine. More interestingly, ammonia borane reduction of GO tetrahydrofuran produced higher nitrogen- and boron-doped graphene that exhibited high supercapacitor performance.

引用

页码：6665 / 6667

页数：3

共 31 条

[1] Amine-boranes:: effective reducing agents for the deracemisation of DL-amino acids using L-amino acid oxidase from Proteus myxofaciens [J].

Alexandre, FR ;

Pantaleone, DP ;

Taylor, PP ;

Fotheringham, IG ;

Ager, DJ ;

Turner, NJ .

TETRAHEDRON LETTERS, 2002, 43 (04) :707-710

[2] Functional Composite Materials Based on Chemically Converted Graphene [J].

Bai, Hua ;

Li, Chun ;

Shi, Gaoquan .

ADVANCED MATERIALS, 2011, 23 (09) :1089-1115

[3] Chemical Reduction of Graphene Oxide to Graphene by Sulfur-Containing Compounds [J].

Chen, Wufeng ;

Yan, Lifeng ;

Bangal, P. R. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (47) :19885-19890

[4] Reduction of graphene oxide with substituted borohydrides [J].

Chua, Chun Kiang ;

Pumera, Martin .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (05) :1892-1898

[5] Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material [J].

Eda, Goki ;

Fanchini, Giovanni ;

Chhowalla, Manish .

NATURE NANOTECHNOLOGY, 2008, 3 (05) :270-274

[6] Facile Synthesis of Graphene Nanosheets via Fe Reduction of Exfoliated Graphite Oxide [J].

Fan, Zhuang-Jun ;

Kai, Wang ;

Yan, Jun ;

Wei, Tong ;

Zhi, Lin-Jie ;

Feng, Jing ;

Ren, Yue-ming ;

Song, Li-Ping ;

Wei, Fei .

ACS NANO, 2011, 5 (01) :191-198

[7] An environmentally friendly and efficient route for the reduction of graphene oxide by aluminum powder [J].

Fan, Zhuangjun ;

Wang, Kai ;

Wei, Tong ;

Yan, Jun ;

Song, Liping ;

Shao, Bo .

CARBON, 2010, 48 (05) :1686-1689

[8] Synthesis of the chemically converted graphene xerogel with superior electrical conductivity [J].

Hai Dinh Pham ;

Viet Hung Pham ;

Tran Viet Cuong ;

Thuy-Duong Nguyen-Phan ;

Chung, Jin Suk ;

Shin, Eun Woo ;

Kim, Sunwook .

CHEMICAL COMMUNICATIONS, 2011, 47 (34) :9672-9674

[9] Generation of B-Doped Graphene Nanoplatelets Using a Solution Process and Their Supercapacitor Applications [J].

Han, Jongwoo ;

Zhang, Li Li ;

Lee, Seungjun ;

Oh, Junghoon ;

Lee, Kyoung-Seok ;

Potts, Jeffrey R. ;

Ji, Junyi ;

Zhao, Xin ;

Ruoff, Rodney S. ;

Park, Sungjin .

ACS NANO, 2013, 7 (01) :19-26

[10] Boron-nitrogen-hydrogen (BNH) compounds: recent developments in hydrogen storage, applications in hydrogenation and catalysis, and new syntheses [J].

Huang, Zhenguo ;

Autrey, Tom .

ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (11) :9257-9268

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