Adsorption of acetaldehyde vapor by activated carbon impregnated with p-aminobenzenesulfonic acid salts

被引:2
作者
Hayashi, T
Kumita, M
Otani, Y
机构
[1] Toyobo Co Ltd, Res Ctr, Otsu, Shiga 5200292, Japan
[2] Kanazawa Univ, Grad Sch Nat Sci & Technol, Dept Chem Engn, Kanazawa, Ishikawa 9201192, Japan
关键词
activated carbon; acetaldehyde; adsorption; p-aminobenzenesulfonic acid salt; impregnation;
D O I
10.1252/kakoronbunshu.31.185
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
p-Aminobenzenesulfonic acid is a potential impregnant on activated carbon for the chemisorption of acetaldehyde vapor. However, because of its low solubility in water, it is difficult to prepare the impregnated activated carbon with a high concentration of p-aminobenzenesulfonic acid. In the present work, activated carbons impregnated with various p-aminobenzenesulfonic acid salts were prepared by soaking three types of activated carbon in aqueous Solution of p-aminobenzenesulfonic acid with various alkali compounds as solubilizing agents. Ammonium hydrogen carbonate was found to be the most Suitable solubilizing agent for the impregnation or p-aminobenzenesulfonic acid. Alkali metal hydroxides reacted with p-aminobenzenesulfonic acid forming p-aminobenzenesulfonic acid alkali metal salts which had no reactivity with acetaldehyde, whereas ammonium hydrogen carbonate produced p-aminobenzenesulfonic acid ammonium salt which had high reactivity with acetaldehyde following the same stoichiometry as that of p-aminobenzenesulfonic acid.
引用
收藏
页码:185 / 191
页数:7
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