Adsorption of acetaldehyde vapor by activated carbon impregnated with p-aminobenzenesulfonic acid salts

被引:2
作者
Hayashi, T
Kumita, M
Otani, Y
机构
[1] Toyobo Co Ltd, Res Ctr, Otsu, Shiga 5200292, Japan
[2] Kanazawa Univ, Grad Sch Nat Sci & Technol, Dept Chem Engn, Kanazawa, Ishikawa 9201192, Japan
关键词
activated carbon; acetaldehyde; adsorption; p-aminobenzenesulfonic acid salt; impregnation;
D O I
10.1252/kakoronbunshu.31.185
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
p-Aminobenzenesulfonic acid is a potential impregnant on activated carbon for the chemisorption of acetaldehyde vapor. However, because of its low solubility in water, it is difficult to prepare the impregnated activated carbon with a high concentration of p-aminobenzenesulfonic acid. In the present work, activated carbons impregnated with various p-aminobenzenesulfonic acid salts were prepared by soaking three types of activated carbon in aqueous Solution of p-aminobenzenesulfonic acid with various alkali compounds as solubilizing agents. Ammonium hydrogen carbonate was found to be the most Suitable solubilizing agent for the impregnation or p-aminobenzenesulfonic acid. Alkali metal hydroxides reacted with p-aminobenzenesulfonic acid forming p-aminobenzenesulfonic acid alkali metal salts which had no reactivity with acetaldehyde, whereas ammonium hydrogen carbonate produced p-aminobenzenesulfonic acid ammonium salt which had high reactivity with acetaldehyde following the same stoichiometry as that of p-aminobenzenesulfonic acid.
引用
收藏
页码:185 / 191
页数:7
相关论文
共 9 条
[1]  
HAYASHI T, 2004, UNPUB ENV SCI TECHNO
[2]   PREPARATION OF ACTIVATED FIBROUS CARBON FROM PHENOLIC FABRIC AND ITS MOLECULAR-SIEVING PROPERTIES [J].
KASAOKA, S ;
SAKATA, Y ;
TANAKA, E ;
NAITOH, R .
NIPPON KAGAKU KAISHI, 1987, (06) :990-1000
[3]   DESIGN OF MOLECULAR-SIEVING CARBON - STUDIES ON ADSORPTION OF VARIOUS DYES IN LIQUID-PHASE [J].
KASAOKA, S ;
SAKATA, Y ;
TANAKA, E ;
NAITOH, R .
NIPPON KAGAKU KAISHI, 1987, (12) :2260-2266
[4]   FORMATION OF ACTIVE CARBONS FROM COKES USING POTASSIUM HYDROXIDE [J].
MARSH, H ;
YAN, DS ;
OGRADY, TM ;
WENNERBERG, A .
CARBON, 1984, 22 (06) :603-611
[5]   CARBONS OF HIGH SURFACE-AREA - A STUDY BY ADSORPTION AND HIGH-RESOLUTION ELECTRON-MICROSCOPY [J].
MARSH, H ;
CRAWFORD, D ;
OGRADY, TM ;
WENNERBERG, A .
CARBON, 1982, 20 (05) :419-426
[6]   Study on development of adsorvent of acetaldehyde [J].
Noda, T ;
Suzuki, M .
KAGAKU KOGAKU RONBUNSHU, 1998, 24 (04) :646-652
[7]  
NODA T, 1999, ADSORPT NEWS, V13, P16
[8]  
NODA T, 2001, NENDO KAGAKU, V41, P75
[9]  
SUGIURA M, 1992, CLAY SCI, V8, P257