Ba0.5Sr0.5Co0.8Fe0.2O3-δ-La0.6Sr0.4Co0.8Fe0.2O3-δ COMPOSITE CATHODE FOR SOLID OXIDE FUEL CEL

被引：11

作者：

Mosialek, M. ^{[1
]}

Kedra, A. ^{[1
]}

Krzan, M. ^{[1
]}

Bielanska, E. ^{[1
]}

Tatko, M. ^{[1
]}

机构：

[1] J Haber Inst Catalysis & Surface Chem PAS, Krakow, Poland

来源：

ARCHIVES OF METALLURGY AND MATERIALS | 2016年 / 61卷 / 03期

关键词：

barium strontium cobalt ferrite; lanthanum strontium cobalt ferrite; solid oxide fuel cell; oxygen reduction reaction; electrochemical impedance spectroscopy; SILVER-MODIFIED BA0.5SR0.5CO0.8FE0.2O3-DELTA; ELECTROCHEMICAL PERFORMANCE; ELECTROLESS DEPOSITION; IT-SOFCS; TEMPERATURE; LA0.6SR0.4CO0.2FE0.8O3-DELTA; CONDUCTIVITY; IMPEDANCE; SYSTEM; CERIA;

D O I：

10.1515/amm-2016-0243

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

Composite cathodes contain Ba0.5Sr0.5Co0.8Fe0.2O3-delta and La0.6Sr0.4Co0.8Fe0.2O3-delta were tested in different configuration for achieving cathode of area specific resistance lower than Ba0.5Sr0.5Co0.8Fe0.2O3-delta and La0.6Sr0.4Co0.8Fe0.2O3-delta cathodes. Electrodes were screen printed on samaria-doped ceria electrolyte half-discs and tested in the three electrode setup by the electrochemical impedance spectroscopy. Microstructure was observed by scanning electron microscopy. The lowest area specific resistance 0.46 and 2.77 W cm(-2) at 700 degrees C and 600 degrees C respectively revealed composite cathode contain Ba0.5Sr0.5Co0.8Fe0.2O3-delta and La0.6Sr0.4Co0.8Fe0.2O3-delta in 1:1 weight ratio. The area specific resistance of this cathode is characterized by the lowest activation energy among tested cathodes.

引用

页码：1137 / 1141

页数：5

共 50 条

[31] Composite cathode materials Ag-Ba0.5Sr0.5Co0.8Fe0.2O3 for solid oxide fuel cells
Mosialek, Michal
Dudek, Magdalena
Michna, Aneta
Tatko, Maciej
Kedra, Aneta
Zimowska, Magorzata
JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2014, 18 (11) : 3011 - 3021
[32] Effect of La0.1Sr0.9Co0.5Mn0.5O3-δ protective coating layer on the performance of La0.6Sr0.4Co0.8Fe0.2O3-δ solid oxide fuel cell cathode
Chou, Ping-Yi
Ciou, Chun-Jing
Lee, Yu-Chen
Hung, I-Ming
JOURNAL OF POWER SOURCES, 2012, 197 : 12 - 19
[33] Diffusion of La and Mn in Ba0.5Sr0.5Co0.8Fe0.2O3-δ polycrystalline ceramics
Harvey, Steven P.
De Souza, Roger A.
Martin, Manfred
ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (02) : 5803 - 5813
[34] Performance of Ba0.5Sr0.5Co0.8Fe0.2O3-δ-Ag composite cathode materials for IT-SOFCs
Zhu, Wenxia
Lu, Zhe
Wang, Lexin
Guan, Xiaoyan
Zhang, Xinyan
ADVANCED MATERIALS AND PROCESSES, PTS 1-3, 2011, 311-313 : 2309 - +
[35] Promoted CO2-poisoning resistance of La0.8Sr0.2MnO3-δ-coated Ba0.5Sr0.5Co0.8Fe0.2O3-δ cathode for intermediate temperature solid oxide fuel cells
Qiu, Peng
Wang, Ao
Li, Jin
Li, Zongbao
Jia, Lichao
Chi, Bo
Pu, Jian
Li, Jian
JOURNAL OF POWER SOURCES, 2016, 327 : 408 - 413
[36] A High-Performance, Nanostructured Ba0.5Sr0.5Co0.8Fe0.2O3-δ Cathode for Solid-Oxide Fuel Cells
Liu, Bin
Chen, Xiaobo
Dong, Yonglai
Mao, Samuel S.
Cheng, Mojie
ADVANCED ENERGY MATERIALS, 2011, 1 (03) : 343 - 346
[37] LaCoO3-δ coated Ba0.5Sr0.5Co0.8Fe0.2O3-δ cathode for intermediate temperature solid oxide fuel cells
Qiu, Peng
Li, Jin
Jia, Lichao
Chi, Bo
Pu, Jian
Li, Jian
Chen, Fanglin
ELECTROCHIMICA ACTA, 2019, 319 : 981 - 989
[38] Thermal and electrical properties of new cathode material Ba0.5Sr0.5Co0.8Fe0.2O3-δ for solid oxide fuel cells
Wei, B
Lü, Z
Li, SY
Liu, YQ
Liu, KY
Su, WH
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2005, 8 (08) : A428 - A431
[39] A screen-printed Ce0.8Sm0.2O1.9 film solid oxide fuel cell with a Ba0.5Sr0.5Co0.8Fe0.2O3-δ cathode
Zhang, Yaohui
Huang, Xiqiang
Lu, Zhe
Liu, Zhiguo
Ge, Xiaodong
Xu, Jiahuan
Xin, Xianshuang
Sha, Xueqing
Su, Wenhui
JOURNAL OF POWER SOURCES, 2006, 160 (02) : 1217 - 1220
[40] Effect of microstructure on oxygen permeation of Ba0.5Sr0.5Co0.8Fe0.2O3-δ and SrCo0.8Fe0.2O3-δ membranes
Klande, Tobias
Ravkina, Olga
Feldhoff, Armin
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2013, 33 (06) : 1129 - 1136

← 1 2 3 4 5 →