Unveiling pseudocapacitive behavior of hard carbon anode materials for sodium-ion batteries

被引：69

作者：

Bobyleva, Zoia V. ^{[1
]}

Drozhzhin, Oleg A. ^{[2
,3
]}

Dosaev, Kirill A. ^{[2
,4
]}

Kamiyama, Azusa ^{[5
]}

Ryazantsev, Sergey V. ^{[3
]}

Komaba, Shinichi ^{[5
]}

Antipov, Evgeny V. ^{[2
,3
]}

机构：

[1] Lomonosov Moscow State Univ, Dept Mat Sci, Moscow 119991, Russia

[2] Lomonosov Moscow State Univ, Dept Chem, Moscow 119991, Russia

[3] Skolkovo Inst Sci & Technol, Skoltech Ctr Energy Sci & Technol, Nobel Str 3, Moscow 143026, Russia

[4] Univ Strasbourg, ICPEES, UMR 7515, 25 Rue Becquerel, F-67087 Strasbourg 2, France

[5] Tokyo Univ Sci, Shinjuku Ku, 1-3 Kagurazaka, Tokyo 1628601, Japan

来源：

ELECTROCHIMICA ACTA | 2020年 / 354卷

基金：

俄罗斯基础研究基金会; 俄罗斯科学基金会;

关键词：

Hard carbon; Anode material; Na-ion batteries; Sodiation mechanism; Pseudocapacity; Intercalation; MECHANISTIC INSIGHTS; TIO2; ANATASE; STORAGE; LITHIUM; PERFORMANCE; INSERTION;

D O I：

10.1016/j.electacta.2020.136647

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Hard carbon is the most prospective anode material for sodium-ion batteries with outstanding electrochemical performance. However, the type of reaction associated with charge storage is a subject of contentious deliberations within the scientific society. We examined the pseudocapacitive behavior of glucose-derived hard carbon with different porosity by detailed linear sweep voltammetric analysis which demonstrated the presence of three distinct processes occurring during Na+-deinsertion. A combination of pseudocapacitive-intercalation-pseudocapacitive behavior for all synthesized hard carbons is proposed. Obtained results differ drastically from the behavior demonstrated by graphite/Li cell, soft carbon/Na cell and pure Na metal plating. (C) 2020 Elsevier Ltd. All rights reserved.

引用

页数：8

共 32 条

[1] Revealing sodium ion storage mechanism in hard carbon [J].

Alvin, Stevanus ;

Yoon, Dohyeon ;

Chandra, Christian ;

Cahyadi, Handi Setiadi ;

Park, Jae-Ho ;

Chang, Wonyoung ;

Chung, Kyung Yoon ;

Kim, Jaehoon .

CARBON, 2019, 145 :67-81

[2] Na-Ion Batteries for Large Scale Applications: A Review on Anode Materials and Solid Electrolyte Interphase Formation [J].

Angel Munoz-Marquez, Miguel ;

Saurel, Damien ;

Luis Gomez-Camer, Juan ;

Casas-Cabanas, Montse ;

Castillo-Martinez, Elizabeth ;

Rojo, Teofilo .

ADVANCED ENERGY MATERIALS, 2017, 7 (20)

[3] New Mechanistic Insights on Na-Ion Storage in Nongraphitizable Carbon [J].

Bommier, Clement ;

Surta, Todd Wesley ;

Dolgos, Michelle ;

Ji, Xiulei .

NANO LETTERS, 2015, 15 (09) :5888-5892

[4] Templated Nanocrystal-Based Porous TiO2 Films for Next-Generation Electrochemical Capacitors [J].

Brezesinski, Torsten ;

Wang, John ;

Polleux, Julien ;

Dunn, Bruce ;

Tolbert, Sarah H. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (05) :1802-1809

[5] Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications [J].

Cao, Yuliang ;

Xiao, Lifen ;

Sushko, Maria L. ;

Wang, Wei ;

Schwenzer, Birgit ;

Xiao, Jie ;

Nie, Zimin ;

Saraf, Laxmikant V. ;

Yang, Zhengguo ;

Liu, Jun .

NANO LETTERS, 2012, 12 (07) :3783-3787

[6] Achieving high energy density and high power density with pseudocapacitive materials [J].

Choi, Christopher ;

Ashby, David S. ;

Butts, Danielle M. ;

DeBlock, Ryan H. ;

Wei, Qiulong ;

Lau, Jonathan ;

Dunn, Bruce .

NATURE REVIEWS MATERIALS, 2020, 5 (01) :5-19

[7] Hard carbons for sodium-ion batteries: Structure, analysis, sustainability, and electrochemistry [J].

Dou, Xinwei ;

Hasa, Ivana ;

Saurel, Damien ;

Vaalma, Christoph ;

Wu, Liming ;

Buchholz, Daniel ;

Bresser, Dominic ;

Komaba, Shinichi ;

Passerini, Stefano .

MATERIALS TODAY, 2019, 23 :87-104

[8] Hydrothermal Cation Exchange Enabled Gradual Evolution of Au@ZnS-AgAuS Yolk-Shell Nanocrystals and Their Visible Light Photocatalytic Applications [J].

Feng, Jingwen ;

Liu, Jia ;

Cheng, Xiaoyan ;

Liu, Jiajia ;

Xu, Meng ;

Zhang, Jiatao .

ADVANCED SCIENCE, 2018, 5 (01)

[9] CRYSTALLITE GROWTH IN GRAPHITIZING AND NON-GRAPHITIZING CARBONS [J].

FRANKLIN, RE .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1951, 209 (1097) :196-&

[10] Correlation of Structure and Performance of Hard Carbons as Anodes for Sodium Ion Batteries [J].

Gomez-Martin, Aurora ;

Martinez-Fernandez, Julian ;

Ruttert, Mirco ;

Winter, Martin ;

Placke, Tobias ;

Ramirez-Rico, Joaquin .

CHEMISTRY OF MATERIALS, 2019, 31 (18) :7288-7299

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