Silica gel-supported tungstosilicic acid: An efficient catalyst for synthesis of diacetals

被引：0

作者：

Jin, Tong-Shou ^{[1
]}

Ma, Guo-Dong ^{[1
]}

Xie, Hong ^{[1
]}

Li, Tong-Shuang ^{[1
]}

机构：

[1] Hebei Univ, Coll Chem & Environm Sci, Baoding 071002, Peoples R China

来源：

ASIAN JOURNAL OF CHEMISTRY | 2008年 / 20卷 / 07期

基金：

中国国家自然科学基金;

关键词：

synthesis; diacetals; pentaerythritol; adehydes; ketones; tungstosilicic acid;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient and convenient method for synthesis of diacetals from aldehydes and ketones with pentaerythritol in refluxing benzene or toluene using silica gel-supported tungstosilicic acid as catalyst is described. This method provides several advantages such as neutral condition, high yields and environment friendly.

引用

页码：5053 / 5059

页数：7

共 19 条

[1]

Backer HJ, 1931, RECL TRAV CHIM PAY-B, V50, P1066

[2] EXCHANGE REACTIONS BETWEEN ALDEHYDEACETALS AND ALDEHYDES .1. [J].

BOGRACHOV, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1950, 72 (05) :2268-2270

[3]

CALLEJAS D, 1998, REV CUB QUIM, V4, P73

[4] Visible light induced photocatalytic reaction of rhodamine B dye via 12-tungstosilicic acid in water [J].

Chen, CC ;

Li, JY ;

Zhao, W ;

Zhao, JC ;

Wan, LJ ;

Xu, YM .

SCIENCE IN CHINA SERIES B-CHEMISTRY, 2003, 46 (06) :577-582

[5] Alkylation of benzene catalysed by supported heteropolyacids [J].

de Angelis, A ;

Amarilli, S ;

Berti, D ;

Montanari, L ;

Perego, C .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 146 (1-2) :37-44

[6] Synthesis of diacetals from aldehydes and ketones with pentaerythritol catalyzed by silica sulfate under microwave irradiation [J].

Jin, TS ;

Wang, HX ;

Wang, KF ;

Li, TS .

SYNTHETIC COMMUNICATIONS, 2004, 34 (16) :2993-2999

[7] Synthesis of diacetals by condensation of carbonyl compounds with bis(hydroxymethyl)-1,3-propanediol catalysed by expansive graphite [J].

Jin, TS ;

Li, TS ;

Zhang, ZH ;

Yuan, YJ .

SYNTHETIC COMMUNICATIONS, 1999, 29 (09) :1601-1606

[8] HETEROPOLY ACIDS AND RELATED-COMPOUNDS AS CATALYSTS FOR FINE CHEMICAL SYNTHESIS [J].

KOZHEVNIKOV, IV .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1995, 37 (02) :311-352

[9]

LU SR, 1999, J JILIN CHEM TECH I, V16, P20

[10]

LUO YM, 2003, CHIN CHEM IND SCI TE, V11, P49

← 1 2 →